Synthesis of functional molecular rod oligomers

被引：7

作者：

Andersen, Casper S.

Gothelf, Kurt V. ^{[1
]}

机构：

[1] Ctr DNA Nanotechnol, Danish Natl Res Fdn, Dept Chem, DK-8000 Aarhus C, Denmark

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2009年 / 7卷 / 01期

关键词：

SOLID-PHASE SYNTHESES; OLIGO(1,4-PHENYLENE ETHYNYLENE)S; ORGANIC-SYNTHESIS; PRECISE LENGTH; WIRES; ELECTRONICS; NANOSTRUCTURES; CONDUCTANCE; COMPONENTS; STRATEGY;

D O I：

10.1039/b815099k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We are presenting the synthesis of a phenylene ethynylene-based rod containing an Fmoc protected amino group and an activated acid which can be applied to peptide couplings. This linear amino acid analogue is applied to the synthesis of di-, tri- and pentamers. The pentamer has a molecular mass of 6.5 kDa and is characterized by H-1 NMR spectroscopy and MALDI- TOF MS. The method has potential for the formation of long macromolecular oligomers.

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收藏

页码：58 / 60

页数：3

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