A Colorimetric and Fluorescent Probe for the Detection of Cu2+ in a Complete Aqueous Solution

被引:0
作者
Xu, Jing [1 ]
Wang, Zuokai [1 ]
Liu, Caiyun [1 ]
Xu, Zhenghe [1 ]
Zhu, Baocun [1 ]
Wang, Ning [1 ]
Wang, Kun [1 ]
Wang, Jiangting [1 ]
机构
[1] Univ Jinan, Shandong Prov Engn Technol Res Ctr Ecol Carbon Si, Sch Resources & Environm, Jinan 250022, Shandong, Peoples R China
关键词
Colorimetric probe; fluorescent probe; copper ion (Cu2+); picolinate; internal charge transfer (ICT); LIVING CELLS; CHEMOSENSOR; CU(II); COPPER; IONS; CHEMODOSIMETER; FLUOROPHORE; SENSORS; ZN2+; PH;
D O I
10.2116/analsci.17P517
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The fluorescent probe has become an important method for the detection of heavy metal ions. In the present work, a new and simple fluorescent probe, Cu-P, for detecting copper ion (Cu2+) was designed and synthesized. The probe has shown high sensitivity and selectivity toward Cu2+. The detection limit was 13 nM (based on the 3 sigma/slope). A significant color change from yellow to pink was observed; thus, the probe Cu-P could serve as a "naked-eye" indicator for Cu2+. Furthermore, the proposed probe was used to detect Cu2+ in real water and soil extract samples, with the result being satisfactory. Therefore, our proposed probe would provide a promising method for the detection of Cu2+ in the environment.
引用
收藏
页码:453 / 457
页数:5
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共 30 条
[1]   Quantitative imaging of selenium, copper, and zinc in thin sections of biological tissues (Slugs-Genus arion) measured by laser ablation inductively coupled of plasma mass spectrometry [J].
Becker, J. S. ;
Matusch, A. ;
Depboylu, C. ;
Dobrowolska, J. ;
Zoriy, M. V. .
ANALYTICAL CHEMISTRY, 2007, 79 (16) :6074-6080
[2]   A coumarin-derived fluorescent chemosensor for selectively detecting Cu2+ : Synthesis, DFT calculations and cell imaging applications [J].
Chen, Fengjuan ;
Liu, Guozhen ;
Shi, Yanjun ;
Xi, Pinxian ;
Cheng, Ju ;
Hong, Jinpeng ;
Shen, Rong ;
Yao, Xiaojun ;
Bai, Decheng ;
Zeng, Zhengzhi .
TALANTA, 2014, 124 :139-145
[3]   Photoluminescence imaging of Zn2+ in living systems [J].
Chen, Yuncong ;
Bai, Yang ;
Han, Zhong ;
He, Weijiang ;
Guo, Zijian .
CHEMICAL SOCIETY REVIEWS, 2015, 44 (14) :4517-4546
[4]   Synthesis of a highly selective bis-rhodamine chemosensor for naked-eye detection of Cu2+ ions and its application in bio-imaging [J].
Chereddy, Narendra Reddy ;
Thennarasu, Sathiah .
DYES AND PIGMENTS, 2011, 91 (03) :378-382
[5]   A new pyrido[1,2-a] benzimidazole-rhodamine FRET system as an efficient ratiometric fluorescent probe for Cu2+ in living cells [J].
Ge, Yanqing ;
Zheng, Xiaoling ;
Ji, Ruixue ;
Shen, Shili ;
Cao, Xiaoqun .
ANALYTICA CHIMICA ACTA, 2017, 965 :103-110
[6]   Peat as a natural solid-phase for copper preconcentration and determination in a multicommuted flow system coupled to flame atomic absorption spectrometry [J].
Gonzales, A. P. S. ;
Firmino, M. A. ;
Nomura, C. S. ;
Rocha, F. R. P. ;
Oliveira, P. V. ;
Gaubeur, I. .
ANALYTICA CHIMICA ACTA, 2009, 636 (02) :198-204
[7]   A two-photon fluorescent probe for Cu2+ based on dansyl moiety and its application in bioimaging [J].
Jiang, Huie ;
Li, Zhijian ;
Kang, Yifan ;
Ding, Liping ;
Qiao, Sen ;
Jia, Shuntian ;
Luo, Weifang ;
Liu, Weisheng .
SENSORS AND ACTUATORS B-CHEMICAL, 2017, 242 :112-117
[8]   A novel selective and sensitive fluorescent turn-on chemodosimeter based on rhodamine hydrazone for copper ions and its application to bioimaging [J].
Jiang, Zhihui ;
Tian, Shujuan ;
Wei, Changqing ;
Ni, Tingjunhong ;
Li, Yan ;
Dai, Li ;
Zhang, Dazhi .
SENSORS AND ACTUATORS B-CHEMICAL, 2013, 184 :106-112
[9]   A new rhodamine B based fluorometric chemodosimeter for Cu2+ ion in aqueous and cellular media [J].
Kempahanumakkagaari, Suresh Kumar ;
Thippeswamy, Ramakrishnappa ;
Malingappa, Pandurangappa .
JOURNAL OF LUMINESCENCE, 2014, 146 :11-17
[10]   A Colorimetric and Fluorescent Chemosensor for the Selective Detection of Cu2+ and Zn2+ Ions [J].
Kim, Min Seon ;
Jo, Tae Geun ;
Ahn, Hye Mi ;
Kim, Cheal .
JOURNAL OF FLUORESCENCE, 2017, 27 (01) :357-367