Well-aligned single-crystalline zinc oxide (ZnO) nanowires with high density were successfully synthesized on nickel monoxide (NiO) catalyzed alumina substrate through a simple metal-vapor deposition method at an extremely low temperature (450degreesC). The single-crystalline ZnO nanowires had a hexagonal wurzite structure and diameters of about 55 mn, and lengths up to 2.6 mum. The photoluminescence spectra under excitation 325 urn showed a ultra-violet (UV) emission at 3.26 eV and a green emission at 2.44 eV. The UV emission and green emission bands were attributed to near band-edge transition and radial combination of a singly ionized oxygen vacancy with a photo-induced hole, respectively. (C) 2002 Elsevier Science B.V. All rights reserved.
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Chen XL, 2000, ADV MATER, V12, P1432, DOI 10.1002/1521-4095(200010)12:19<1432::AID-ADMA1432>3.0.CO