Synthesis, Structure, and Some Chemical Properties of Diferrocenyl-1,2,3-triazines

被引：5

作者：

Klimova, Elena I. ^{[1
]}

Klimova, Tatiana ^{[1
]}

Flores Alamo, Marcos ^{[1
]}

Mendez Iturbide, Daniel ^{[2
]}

Martinez Garcia, Marcos ^{[3
]}

机构：

[1] Univ Nacl Autonoma Mexico, Fac Quim, Mexico City 04510, DF, Mexico

[2] Univ Autonoma Tlaxcala, Fac Ciencias Salud, San Pablo Del Monte 90720, Tlaxcala, Mexico

[3] Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04510, DF, Mexico

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 2009年 / 46卷 / 03期

关键词：

POLYHALOGENOHETEROCYCLIC COMPOUNDS; NUCLEOPHILIC-ATTACK; PYROLYSIS;

D O I：

10.1002/jhet.93

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reactions of 1-amino-2,3-diferrocenylcyclopropenylium tetrafluoroborate (5a-c) or 2,3-diferrocenyl-l-methylthiocyclopropenylium iodide with sodium azide afford 5-methylthino-4,6-diferrocenyl-1,2,3-triazines (7a-c) or 5-methylthio-4,6-diferrocenyl- and 4-methylthio-5,6-diferrocenyl-1,2,3-triazines (8a and 8b), respectively. Their structures were established using spectroscopic methods and that of compound 8a was confirmed using X-ray diffraction analysis. Triazines 5a-c react with alkyl iodides to yield N(2)- and N-alkyl-C(5)-derivatives. Their alkaline hydrolysis results in 2-methyl-4,6-diferrocenyl-2,5dihydro-1,2,3-triazin-5-one (16) and 4,6-diferrocenyl-5-hydroxy-1,2,3-triazine (17).

引用

页码：477 / 483

页数：7