Synthesis of indenyl ethers by gold(I)-catalyzed intramolecular carboalkoxylation of alkynes

被引：191

作者：

Dube, Pascal ^{[1
]}

Toste, F. Dean ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 37期

关键词：

D O I：

10.1021/ja064209+

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The gold(I)-catalyzed carboalkoxylation of alkynes to form indanone derivatives from readily available ortho-acetylenic benzylic ethers is described. Importantly, the gold(I)-catalyzed rearrangement of enantioenriched benzylic ethers proceeds with chirality transfer, thus providing a practical method for the enantioselective synthesis of indenyl ethers. Copyright © 2006 American Chemical Society.

引用

页码：12062 / 12063

页数：2

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