Mechanochemical and solvent-free assembly of zirconium-based metal-organic frameworks

被引：253
作者：
Uzarevic, Krunoslav [2 ]
Wang, Timothy C. [3 ,4 ]
Moon, Su-Young [3 ,4 ]
Fidelli, Athena M. [1 ]
Hupp, Joseph T. [3 ,4 ]
Farha, Omar K. [3 ,4 ,5 ]
Friscic, Tomislav [1 ]
机构：
[1] McGill Univ, Dept Chem, 801 Sherbrooke St W, Montreal, PQ H3A 0B8, Canada
[2] Rudjer Boskovic Inst, Zagreb, Croatia
[3] Northwestern Univ, Dept Chem, 2145 Sheridan Rd, Evanston, IL 60208 USA
[4] Northwestern Univ, Int Inst Nanotechnol, Evanston, IL 60208 USA
[5] King Abdulaziz Univ, Fac Sci, Dept Chem, Jeddah, Saudi Arabia
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 10期
基金：
加拿大自然科学与工程研究理事会;
关键词：
X-RAY-DIFFRACTION; FACILE SYNTHESIS; ADSORPTION; STABILITY; MOFS; STORAGE; UIO-66; OPPORTUNITIES; PHOTOCATALYST; HYDROGEN;
D O I：
10.1039/c5cc08972g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We develop the first mechanochemical and solvent-free routes for zirconium metal-organic frameworks, making the frameworks UiO-66 and UiO-66-NH2 accessible on the gram scale without strong acids, high temperatures or excess reactants. The frameworks form either by milling, or spontaneous self-assembly by simply exposing solid mixtures of reactants to organic vapour. The generated frameworks exhibit high porosity and catalytic activity in the hydrolysis of model nerve agents, on par with their solvothermally generated counterparts.
引用
收藏
页码：2133 / 2136
页数：4
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