Mechanochemical and solvent-free assembly of zirconium-based metal-organic frameworks

被引：264

作者：

Uzarevic, Krunoslav ^{[2
]}

Wang, Timothy C. ^{[3
,4
]}

Moon, Su-Young ^{[3
,4
]}

Fidelli, Athena M. ^{[1
]}

Hupp, Joseph T. ^{[3
,4
]}

Farha, Omar K. ^{[3
,4
,5
]}

Friscic, Tomislav ^{[1
]}

机构：

[1] McGill Univ, Dept Chem, 801 Sherbrooke St W, Montreal, PQ H3A 0B8, Canada

[2] Rudjer Boskovic Inst, Zagreb, Croatia

[3] Northwestern Univ, Dept Chem, 2145 Sheridan Rd, Evanston, IL 60208 USA

[4] Northwestern Univ, Int Inst Nanotechnol, Evanston, IL 60208 USA

[5] King Abdulaziz Univ, Fac Sci, Dept Chem, Jeddah, Saudi Arabia

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 10期

基金：

加拿大自然科学与工程研究理事会;

关键词：

X-RAY-DIFFRACTION; FACILE SYNTHESIS; ADSORPTION; STABILITY; MOFS; STORAGE; UIO-66; OPPORTUNITIES; PHOTOCATALYST; HYDROGEN;

D O I：

10.1039/c5cc08972g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We develop the first mechanochemical and solvent-free routes for zirconium metal-organic frameworks, making the frameworks UiO-66 and UiO-66-NH2 accessible on the gram scale without strong acids, high temperatures or excess reactants. The frameworks form either by milling, or spontaneous self-assembly by simply exposing solid mixtures of reactants to organic vapour. The generated frameworks exhibit high porosity and catalytic activity in the hydrolysis of model nerve agents, on par with their solvothermally generated counterparts.

引用

页码：2133 / 2136

页数：4

共 74 条

[1] Reverse shape selectivity in the adsorption of hexane and xylene isomers in MOF UiO-66 [J].

Barcia, Patrick S. ;

Guimaraes, Daniela ;

Mendes, Patricia A. P. ;

Silva, Jose A. C. ;

Guillerm, Vincent ;

Chevreau, Hubert ;

Serre, Christian ;

Rodrigues, Alirio E. .

MICROPOROUS AND MESOPOROUS MATERIALS, 2011, 139 (1-3) :67-73

[2] Rapid Room-Temperature Synthesis of Zeolitic Imidazolate Frameworks by Using Mechanochemistry [J].

Beldon, Patrick J. ;

Fabian, Laszlo ;

Stein, Robin S. ;

Thirumurugan, A. ;

Cheetham, Anthony K. ;

Friscic, Tomislav .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (50) :9640-9643

[3] Mechanochemistry of inorganic and organic systems: what is similar, what is different? [J].

Boldyreva, Elena .

CHEMICAL SOCIETY REVIEWS, 2013, 42 (18) :7719-7738

[4] Zr- and Hf-Based Metal-Organic Frameworks: Tracking Down the Polymorphism [J].

Bon, Volodymyr ;

Senkovska, Irena ;

Baburin, Igor A. ;

Kaskel, Stefan .

CRYSTAL GROWTH & DESIGN, 2013, 13 (03) :1231-1237

[5] Mechanochemical preparation of molecular and supramolecular organometallic materials and coordination networks [J].

Braga, D ;

Giaffreda, SL ;

Grepioni, F ;

Pettersen, A ;

Maini, L ;

Curzi, M ;

Polito, M .

DALTON TRANSACTIONS, 2006, 6 (10) :1249-1263

[6] Solvent effect in a "solvent free" reaction [J].

Braga, Dario ;

Giaffreda, Stefano Luca ;

Grepioni, Fabrizia ;

Chierotti, Michele R. ;

Gobetto, Roberto ;

Palladino, Giuseppe ;

Polito, Marco .

CRYSTENGCOMM, 2007, 9 (10) :879-881

[7] Improved Synthesis of a Zirconium(IV) Muconate Metal-Organic Framework: Characterization, Stability and Gas Sorption Properties [J].

Buragohain, Amlan ;

Biswas, Shyam .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2015, (14) :2463-2468

[8] Water Stability and Adsorption in Metal-Organic Frameworks [J].

Burtch, Nicholas C. ;

Jasuja, Himanshu ;

Walton, Krista S. .

CHEMICAL REVIEWS, 2014, 114 (20) :10575-10612

[9] A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability [J].

Cavka, Jasmina Hafizovic ;

Jakobsen, Soren ;

Olsbye, Unni ;

Guillou, Nathalie ;

Lamberti, Carlo ;

Bordiga, Silvia ;

Lillerud, Karl Petter .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (42) :13850-13851

[10] Chemical Environment Control and Enhanced Catalytic Performance of Platinum Nanoparticles Embedded in Nanocrystalline Metal-Organic Frameworks [J].

Choi, Kyung Min ;

Na, Kyungsu ;

Somorjai, Gabor A. ;

Yaghi, Omar M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (24) :7810-7816

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