共 32 条
Morphology alterations during postsynthesis oxidation of Zn nanowires
被引:7
作者:
Schroeder, P.
[1
]
Kast, M.
[1
]
Halwax, E.
[2
]
Edtmaier, C.
[2
]
Bethge, O.
[3
]
Brueckl, H.
[1
]
机构:
[1] Austrian Res Ctr GmbH ARC, Div Nano Syst Technol, A-1220 Vienna, Austria
[2] Vienna Univ Technol, Inst Chem Technol & Analyt, A-1060 Vienna, Austria
[3] Vienna Univ Technol, Inst Solid State Elect, A-1040 Vienna, Austria
关键词:
grain growth;
II-VI semiconductors;
nanofabrication;
nanowires;
oxidation;
scanning electron microscopy;
solid-state phase transformations;
wide band gap semiconductors;
X-ray diffraction;
zinc;
zinc compounds;
ZINC-OXIDE NANOWIRES;
FABRICATION;
SUBSTRATE;
D O I:
10.1063/1.3126519
中图分类号:
O59 [应用物理学];
学科分类号:
摘要:
Zinc metal nanowires have been oxidized at temperatures of 200-500 degrees C in ambient air in order to obtain ZnO nanowires. X-ray diffraction investigations reveal a complete transformation from Zn to ZnO at a temperature of >= 300 degrees C within 30 min. Temperature-induced grain growth attains saturation at about 350 degrees C. Scanning electron microscopy studies show a pronounced morphology change from smooth, unidirectional to rough, bursted nanorods at a temperature of >250 degrees C. The corresponding transformation mechanism is discussed.
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