Permselectivity of 4-aminophenol, paracetanol and phenacetin on the self-assembled n-alkanethiol monolayer modified gold electrode

被引：0

作者：

Li, JH ^{[1
]}

Liu, ZM ^{[1
]}

Dong, SJ ^{[1
]}

Wang, EK ^{[1
]}

机构：

[1] CHINESE ACAD SCI,CHANGCHUN INST APPL CHEM,ELECTROANALYT CHEM LAB,CHANGCHUN 130022,PEOPLES R CHINA

来源：

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES | 1996年 / 12卷 / 04期

关键词：

permselectivity; self-assembled monolayer; hydrophobicity; phenacetin; paracetanol; 4-aminophenol;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The gold electrodes coated by n-alkanethiol with various chain lengths were used to study the permeability of uric acid, ascorbic acid, 4-aminophenol, paracetanol and phenacetin by means of linear sweep voltammetry. The results show that the optimum chain length is n=10. The improvements in the selectivity and the stability of the amperometric detection of these compounds in a flow stream were obtained by n-alkanethiol self assembled monolayers modified electrodes based on their differences in the hydrophobicity and the permeability.

引用

页码：340 / 347

页数：8

共 27 条

[1] ELECTROCHEMISTRY AT OMEGA-HYDROXY THIOL COATED ELECTRODES .3. VOLTAGE INDEPENDENCE OF THE ELECTRON-TUNNELING BARRIER AND MEASUREMENTS OF REDOX KINETICS AT LARGE OVERPOTENTIALS [J].

BECKA, AM ;

MILLER, CJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (06) :2657-2668

[2] QUANTITATIVE-DETERMINATION OF GLUTATHIONE, CYSTEINE, AND N-ACETYL CYSTEINE CONJUGATES OF ACETAMINOPHEN BY HIGH-PRESSURE LIQUID-CHROMATOGRAPHY [J].

BUCKPITT, AR ;

ROLLINS, DE ;

NELSON, SD ;

FRANKLIN, RB ;

MITCHELL, JR .

ANALYTICAL BIOCHEMISTRY, 1977, 83 (01) :168-177

[3] RAPID HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHIC ASSAY OF ACETAMINOPHEN IN SERUM AND TISSUE-HOMOGENATES [J].

COLIN, P ;

SIROIS, G ;

CHAKRABARTI, S .

JOURNAL OF CHROMATOGRAPHY-BIOMEDICAL APPLICATIONS, 1987, 413 :151-160

[4] CONSEQUENCES OF MICROSCOPIC SURFACE-ROUGHNESS FOR MOLECULAR SELF-ASSEMBLY [J].

CREAGER, SE ;

HOCKETT, LA ;

ROWE, GK .

LANGMUIR, 1992, 8 (03) :854-861

[5] SYNTHESIS, STRUCTURE, AND PROPERTIES OF MODEL ORGANIC-SURFACES [J].

DUBOIS, LH ;

NUZZO, RG .

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1992, 43 :437-463

[6] PHENACETIN ESTIMATION FROM BIOLOGICAL SAMPLES BY HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY [J].

DUGGIN, GG .

JOURNAL OF CHROMATOGRAPHY, 1976, 121 (01) :156-160

[7]

FORSTER RJ, 1994, J AM CHEM SOC, V116, P544

[8]

HEILBRON I, 1953, DICT ORGANIC COMPOUN

[9]

JI H, 1988, SEPU, V6, P1525

[10] CHARACTERIZATION OF MULTIPLE CARBON-FIBER MICROELECTRODES IN A FLOW-THROUGH CELL AND AMPEROMETRIC DETECTION WITH DILUTE ELECTROLYTE FOR LIQUID-CHROMATOGRAPHY [J].

JI, HM ;

HE, J ;

DONG, SJ ;

WANG, EK .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1990, 290 (1-2) :93-103

← 1 2 3 →