A simple electrospray interface based on a DC ion carpet

被引:17
作者
Anthony, Staci N. [1 ]
Shinholt, Deven L. [1 ]
Jarrold, Martin F. [1 ]
机构
[1] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA
基金
美国国家科学基金会;
关键词
Electrospray interface; Ion carpet; Trajectory calculations; MULTICAPILLARY INLET; ATMOSPHERIC-PRESSURE; FUNNEL; SIMULATIONS;
D O I
10.1016/j.ijms.2014.06.007
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
We describe a simple electrospray interface incorporating a long drift region and a DC ion carpet. The function of the drift region is to thermalize and desolvate the ions. It has a series of ring electrodes supplied with RF and DC voltages, which radially confine and transport ions towards the DC ion carpet. The DC ion carpet consists of a series of concentric rings on a planar printed circuit board, which provide a DC potential gradient that funnels ions through a central aperture. The design and operating parameters were optimized by trajectory calculations and experiments. According to calculations, the transmission efficiency for thermalized ions exceeds 90%, and there is little m/z discrimination at the exit aperture. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:1 / 7
页数:7
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