Dehydration Kinetics of Tincalconite from Thermogravimetric Data

被引：0

作者：

Scvim, Fatih ^{[1
]}

Kucukarslan, Hilal ^{[2
]}

Demir, Fatih ^{[1
]}

Eroglu, Hayrettin ^{[3
]}

Aktan, Mehmet ^{[4
]}

机构：

[1] Ataturk Univ, Fac Engn, Dept Chem Engn, TR-25240 Erzurum, Turkey

[2] TSFAS, Dept Res & Dev, Kirsehir, Turkey

[3] Ataturk Univ, Fac Engn, Dept Biomed Engn, TR-25240 Erzurum, Turkey

[4] Ataturk Univ, Fac Engn, Dept Ind Engn, TR-25240 Erzurum, Turkey

来源：

JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN | 2014年 / 36卷 / 02期

关键词：

Tincalconite; Thermal Decomposition; Suzuki Method and Coats-Redfern Method; THERMAL-DECOMPOSITION; PARAMETERS; ULEXITE;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Kinetic parameters of tincalconite during thermal decomposition were explored with TGA data. Coats-Redfern and Suzuki methods were implemented for the kinetics analysis. Decomposition kinetics of tincalconite occurred in two steps and both suitably fit a first-order kinetic model. Activation energy and frequency factor were observed as 149.17 kJ.mol(-1) and 1.2x10(16) min(-1) for region I, and 5.45 kJ.mol(-1) and 5.23x10(8) min(-1) for region II, respectively with the Coats-Redfern method. Activation energy and frequency factor were observed as 60.95 kJ.mol(-1) and 67.21x10(5) min(-1), respectively for the Suzuki method.

引用

页码：227 / 231

页数：5

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