Colloidal Nanoclusters of MgO Coated with Alkali Metal Nitrates/Nitrites for Rapid, High Capacity CO2 Capture at Moderate Temperature

Colloidal nanoclusters of metal oxides constitute a promising new class of building blocks for a range of advanced functional materials. Herein, we report on the development of colloidal nanoclusters of MgO for CO2 capture prepared by a novel nonhydrolytic sol-gel reaction followed by the deposition of alkali metal salts by methanol evaporation-induced surface precipitation. The CO2 uptake exceeded 11.7 mmol g(-1) (514.8 mg CO2 per 1 g of adsorbent) in 30 min in the presence of 100% dry CO2 under ambient pressure (1 bar) at 340 degrees C and reached 15.7 mmol g(-1) (690.8 mg CO2 per 1 g of adsorbent) in 4 h. Colloidal nanoclusters possessing multiple inner grain boundaries and rough surfaces allowed for a dramatic increase in active surface area of MgO coated with thin layers of alkali metal salts and enabled the rapid conversion of MgO to MgCO3 with high conversion ratio. It was also discovered that the CO2 uptake loading and the regenerability of the sorbents can be enhanced on introduction of nitrite salts to the coating layer through the formation of magnesium nitro or nitrate species, which increased the critical thickness of product layers and mitigated the degradation of nanodusters over the repeated sorption/desorption cycles.