Hydrothermal synthesis, crystal structure, and luminescent property of a new Cd(II) coordination polymer with fourfold interpenetrated diamond topology

被引：0

作者：

Yu, Zhiying ^{[1
]}

机构：

[1] Weihai Vocat Coll, Dept Biol Chem Engn, Weihai 264210, Shandong, Peoples R China

来源：

INORGANIC AND NANO-METAL CHEMISTRY | 2017年 / 47卷 / 02期

关键词：

Cd(II); coordination polymer; crystal structure; METAL-ORGANIC FRAMEWORK; LIGAND; ANIONS;

D O I：

10.1080/15533174.2016.1186037

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Under hydrothermal condition, a new Cd(II) coordination polymer, [and bib =], has been synthesized with mixed organic ligands. Complex, {[Cd(cda)(L)]center dot 2H(2)O} n(1) (H(2)cda = 1,4-cyclohexane dicarboxylic acid and L D 1,4-bis (2-methyl imidazol-3-ium-yl) benzene), is monoclinic, space group P2/c with a = 13.312(3), b = 7.316(4), c = 14.870(3) angstrom, V = 1447.8(12) angstrom(3), Z = 2, M-r = 556.88, D-c = 1.277g/cm(3), F(000) = 568, and mu = 0.791 mm(-1). The final refinement gave R = 0.0470and wR = 0.0505 for 4,492 reflections with I > 2 sigma(I). Single crystal X-ray analysis reveals that complex 1 features a three-dimensional structure with a fourfold interpenetrating diamondoid net. Furthermore the solid state luminescent property of title complex 1 was investigated at room temperature in the solid state.

引用

页码：294 / 297

页数：4

共 19 条

[1]

Blatov V. A., 1999, TOPOS 4 0

[2]

Carlucci L, 2002, CHEM-EUR J, V8, P1519, DOI 10.1002/1521-3765(20020402)8:7<1519::AID-CHEM1519>3.0.CO

[3]

2-5

[4] A new acylamide MOF showing uncommon ten-fold interpenetration [J].

Dang, Li-long ;

Li, Jian-qiang ;

Liu, Shu-juan ;

Luo, Ming-biao ;

Luo, Feng .

INORGANIC CHEMISTRY COMMUNICATIONS, 2014, 45 :30-32

[5] Utility and synthetic uses of Mannich reaction: An efficient route for synthesis of thiadiazino-[1,3,5][3,2-a]benzimidazoles [J].

El-Wareth, A ;

Sarhan, AO ;

Abdel-Hafez, SH ;

El-Sherief, H ;

Aboel-Fadl, T .

SYNTHETIC COMMUNICATIONS, 2006, 36 (08) :987-996

[6] A chiral 3D polymer with right- and left-helices based on 2,2′-biimidazole:: Synthesis, crystal structure and fluorescent property [J].

Fu, Yao-Mei ;

Zhao, Ya-Hui ;

Lan, Ya-Qian ;

Wang, Yong ;

Qiu, Yong-Qing ;

Shao, Kul-Zhan ;

Su, Zhong-Min .

INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (06) :720-723

[7] Tuning structural topologies of four Ni(II) coordination polymers through modifying the substitute group of organic ligand [J].

Guo, Feng ;

Zhu, Baoyong ;

Liu, Mingli ;

Zhang, Xiuling ;

Zhang, Jian ;

Zhao, Jiongpeng .

CRYSTENGCOMM, 2013, 15 (31) :6191-6198

[8] N-Heterocyclic Carbene-Like Catalysis by a Metal-Organic Framework Material [J].

Lalonde, Marianne B. ;

Farha, Omar K. ;

Scheidt, Karl A. ;

Hupp, Joseph T. .

ACS CATALYSIS, 2012, 2 (08) :1550-1554

[9] Coordination polymers constructed from an asymmetric biphenyl-dicarboxylate and N-donor ligands: structures and photoluminescent properties [J].

Man, Zengming ;

Guo, Feng .

JOURNAL OF COORDINATION CHEMISTRY, 2013, 66 (01) :1-8

[10] Coordination polymers based on a flexible bis(triazole) ligand and aromatic polycarboxylate anions: syntheses, topological structures and photoluminescent properties [J].

Mu, Yajuan ;

Han, Gang ;

Ji, Shuying ;

Hou, Hongwei ;

Fan, Yaoting .

CRYSTENGCOMM, 2011, 13 (19) :5943-5950

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