Synthesis of new spiropyrans with a polyaromatic of heteroaromatic pendant and their photochromic behaviors

被引：0
|
作者：
Pang, ML [1 ]
Nie, YT [1 ]
Wang, YM [1 ]
Meng, JB [1 ]
Wang, JT [1 ]
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2002年 / 20卷 / 10期
关键词：
spiropyran; photochromism; UV-absorption spectrum;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A series of spiropyrans with a polyaromatic or heteroaromatic pendant was synthesized conveniently. Their photochromic behaviors were investigated with the aid of absorption spectral measurements. The results indicated that the compounds with the same parent spiropyran but different aromatic pendant show significantly different photochronic properties. This may be due to the pi-pi orbital interaction between the polyaromatic pendant and the open photomerocyanine form of spiropyran. The results obtained are very useful in the molecule design area.
引用
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页码：1102 / 1108
页数：7
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