Mechanochemical modification of peat humic acids

被引:6
作者
Savel'eva, A. V. [1 ]
Yudina, N. V. [1 ]
机构
[1] Russian Acad Sci, Inst Petr Chem, Siberian Branch, Tomsk 634021, Russia
关键词
Catalyst activity - Biological materials - Organic acids - Iron compounds - Transition metals;
D O I
10.3103/S0361521914050127
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
It was demonstrated that the mechanochemical modification of humic acids in the presence of iron oxyhydroxides facilitated the occurrence of solid-phase reactions due to an increase in the concentrations of phenol, carboxyl, and methoxy groups and quinoid fragments. The modified humic acids possessed an increased catalytic activity caused by the presence of quinoid fragments, phenol hydroxyls, and the humic complexes of transition metals.
引用
收藏
页码:328 / 331
页数:4
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