The synthesis and crystal structure of two new isopolyoxoanion complexes:: [M2(DMF)12(Mo6O19)2] (M = Co, Ni, DMF = dimethylformamide)

被引：9

作者：

Guo, YQ ^{[1
]}

Wang, XL ^{[1
]}

Li, YG ^{[1
]}

Wang, EB ^{[1
]}

Xu, L ^{[1
]}

Hu, CW ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2004年 / 57卷 / 06期

基金：

中国国家自然科学基金;

关键词：

isopolyoxoanions; transition metal; crystal structure; synthesis;

D O I：

10.1080/00958970410001671084

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two solid-state materials, {M-2(DMF)(12)[Mo6O19](2)} (M = Co, Ni, DMF = dimethylformamide), have been designed, synthesized under mild reaction conditions and characterized by elemental analyses, IR spectra and single crystal X-ray diffraction. The structures exhibit extended 2D networks through hydrogen bonds among polyanions and [M(DMF)(6)](2+); hydrogen-bonding interactions are responsible for the stability of the crystal.

引用

页码：445 / 451

页数：7

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