The first uranyl-methine carbon bond; a complex with out-of-plane uranyl equatorial coordination

被引：53

作者：

Sarsfield, MJ ^{[1
]}

Helliwell, M ^{[1
]}

Collison, D ^{[1
]}

机构：

[1] Univ Manchester, Dept Chem, Ctr Radiochem Res, Manchester M13 9PL, Lancs, England

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 19期

关键词：

D O I：

10.1039/b206889c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of [UO2Cl2( thf)(3)] in thf with one equivalent of [Na{CH(Ph2P = NSiMe3)(2)}] yields an unusual uranyl chloro-bridged dimer containing a uranium( VI)-carbon bond as part of a tridentate bis(iminophosphorano) methanide chelate complex. The methine carbon is displaced significantly from the uranyl equatorial plane.

引用

页码：2264 / 2265

页数：2

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