Iron Polyoxometalate Single-Molecule Magnets

被引：192

作者：

Compain, Jean-Daniel ^{[1
]}

Mialane, Pierre ^{[1
]}

Dolbecq, Anne ^{[1
]}

Mbomekalle, Israel Martyr ^{[1
]}

Marrot, Jerome ^{[1
]}

Secheresse, Francis ^{[1
]}

Riviere, Eric ^{[2
]}

Rogez, Guillaume ^{[3
]}

Wernsdorfer, Wolfgang ^{[4
,5
]}

机构：

[1] Univ Versailles St Quentin, Inst Lavoisier Versailles, UMR 8180, F-78035 Versailles, France

[2] Univ Paris 11, Equipe Chim Inorgan, Inst Chim Mol & Met Orsay, UMR 8182, F-91405 Orsay, France

[3] Univ Strasbourg, CNRS, IPCMS, UMR 7504, F-67070 Strasbourg, France

[4] Univ Grenoble 1, Grenoble 9, France

[5] CNRS, Inst Neel, Grenoble 9, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 17期

关键词：

electrochemistry; iron; polyoxometalates; single-molecule magnets; FE-III; COBALT(II) CLUSTER; CU-II; MAGNETIZATION; TUNGSTOPHOSPHATE; CHEMISTRY; COMPLEX; SALTS;

D O I：

10.1002/anie.200900117

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Iron sandwich on a tungstate bun: Two new polyoxotungstates with paramagnetic iron(III) heteroatoms (see structure, W blue, Fe yellow, O red) possess S=15/2 and S=5 ground states. Both compounds are single-molecule magnets, and the hexairon species shows large hysteresis (see picture) and quantum tunneling effects at low temperature. Electrochemical studies indicate that these species are stable in solution for a wide range of pH values. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3077 / 3081

页数：5

共 43 条

[21] MAGNETOSTRUCTURAL CORRELATIONS IN MAGNETICALLY COUPLED (MU-OXO)DIIRON(III) COMPLEXES [J].

GORUN, SM ;

LIPPARD, SJ .

INORGANIC CHEMISTRY, 1991, 30 (07) :1625-1630

[22] Quantum tunneling of magnetization in lanthanide single-molecule magnets: Bis(phthalocyaninato)terbium and bis(phthalocyaninato)dysprosium anions [J].

Ishikawa, N ;

Sugita, M ;

Wernsdorfer, W .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (19) :2931-2935

[23] Lanthanide double-decker complexes functioning as magnets at the single-molecular level [J].

Ishikawa, N ;

Sugita, M ;

Ishikawa, T ;

Koshihara, S ;

Kaizu, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (29) :8694-8695

[24] Electron transfer behavioir of multi-iron sandwich-type polyoxometalates and electrocatalytic reduction reactions [J].

Keita, B ;

Mbomekalle, IM ;

Lu, YW ;

Nadjo, L ;

Berthet, P ;

Anderson, TM ;

Hill, CL .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (17) :3462-3475

[25]

Keita B., 2006, ENCY ELECTROCHEMISTR, V7, P607

[26] Syntheses and X-ray characterization of novel [M4(H2O)2(XW9O34)2]n- (M = CuII, X = CuII; and M = FeIII, X = FeIII) polyoxotungstates [J].

Limanski, EM ;

Piepenbrink, M ;

Droste, E ;

Burgemeister, K ;

Krebs, B .

JOURNAL OF CLUSTER SCIENCE, 2002, 13 (03) :369-379

[27] The wheel-shaped Cu20 tungstophosphate [Cu20Cl(OH)24(H2O)12(P8W48O184)]25- ion [J].

Mal, SS ;

Kortz, U .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (24) :3777-3780

[28] Structure, magnetism, and electrochemistry of the multinickel polyoxoanions [Ni6As3W24O94(H2O)2]17-, [Ni3Na(H2O)2(AsW9O34)2]11-, and [Ni4Mn2P3W24O94(H2O)17- [J].

Mbomekalle, IM ;

Keita, B ;

Nierlich, M ;

Kortz, U ;

Berthet, P ;

Nadjo, L .

INORGANIC CHEMISTRY, 2003, 42 (17) :5143-5152

[29] Multi-iron tungstodiarsenates.: Synthesis, characterization, and electrocatalytic studies of αββα-(FeIIIOH2)2FeIII2(AS2W15O56)2 12- [J].

Mbomekalle, IM ;

Keita, B ;

Nadjo, L ;

Berthet, P ;

Hardcastle, KI ;

Hill, CL ;

Anderson, TM .

INORGANIC CHEMISTRY, 2003, 42 (04) :1163-1169

[30] A supramolecular tetradecanudear copper(II) polyoxotungstate [J].

Mialane, P ;

Dolbecq, A ;

Marrot, J ;

Rivière, E ;

Sécheresse, F .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (30) :3523-3526

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