Fabrication and Characterization of In Situ Porous Si3N4-Si2N2O-BN Ceramic

被引:22
作者
Wang, Shengjin [1 ]
Yang, Zhihua [1 ]
Duan, Xiaoming [1 ]
Jia, Dechang [1 ]
Ma, Feixiang [1 ]
Sun, Boqian [1 ]
Zhou, Yu [1 ]
机构
[1] Harbin Inst Technol, Inst Adv Ceram, Harbin 150001, Peoples R China
基金
中国国家自然科学基金;
关键词
SILICON-NITRIDE; MECHANICAL-PROPERTIES; DIELECTRIC-PROPERTIES; COMPRESSIVE STRENGTH; MICROSTRUCTURE; BEHAVIOR; SIZE;
D O I
10.1111/ijac.12134
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Porous Si3N4-Si2N2O-BN ceramic was fabricated at 1750 degrees C using Si3N4, BN, and (NH4)(2)HPO4 as starting materials. During the sintering process, oxygen from the decomposed products of (NH4)(2)HPO4 would bond Si and N in the liquid phase to form Si2N2O. The microstructure and properties of the porous ceramics were investigated. With the (NH4)(2)HPO4 content varied from 10 to 50 vol.%, porosity of the porous Si3N4-Si2N2O-BN ceramic increased from 43.5% to 51%. The microstructure, mechanical, and dielectric properties was well controlled by adjusting (NH4)(2)HPO4 contents. The present technique offers a more simple way of synthesizing porous Si3N4-Si2N2O-BN ceramics.
引用
收藏
页码:832 / 838
页数:7
相关论文
共 35 条
[21]   OXYGEN CONTENT OF ALPHA SILICON-NITRIDE [J].
PRIEST, HF ;
BURNS, FC ;
PRIEST, GL ;
SKAAR, EC .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1973, 56 (07) :395-395
[22]   New synthesis route for Si2N2O ceramics based on desert sand [J].
Radwan, M ;
Kashiwagi, T ;
Miyamoto, Y .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2003, 23 (13) :2337-2341
[23]   Silicon nitride and related materials [J].
Riley, FL .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2000, 83 (02) :245-265
[25]   Effects of weak boundary phases (WBP) on the microstructure and mechanical properties of pressureless sintered Al2O3/h-BN machinable composites [J].
Shi, Zhongqi ;
Wang, Jiping ;
Qiao, Guanjun ;
Jin, Zhihao .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2008, 492 (1-2) :29-34
[26]   Preparation and properties of machinable Si2N2O/BN composites [J].
Tong, Qingfeng ;
Zhou, Yanchun ;
Zhang, Jie ;
Wang, Jingyang ;
Li, Meisuan ;
Li, Zhongping .
INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY, 2008, 5 (03) :295-304
[27]  
Wang CM, 1998, J AM CERAM SOC, V81, P1125, DOI 10.1111/j.1151-2916.1998.tb02459.x
[28]   Effect of BN content on microstructures, mechanical and dielectric properties of porous BN/Si3N4 composite ceramics prepared by gel casting [J].
Wang, Shengjin ;
Jia, Dechang ;
Yang, Zhihua ;
Duan, Xiaoming ;
Tian, Zhuo ;
Zhou, Yu .
CERAMICS INTERNATIONAL, 2013, 39 (04) :4231-4237
[29]  
Xia Y. F., 2012, MATER DESIGN, V33, P8
[30]   Microstructure and mechanical properties of superplastically deformed silicon nitride-silicon oxynitride in situ composites [J].
Xie, RJ ;
Mitomo, M ;
Xu, FF ;
Zhan, GD ;
Bando, Y ;
Akimune, Y .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2002, 22 (06) :963-971