Fabrication and Characterization of In Situ Porous Si3N4-Si2N2O-BN Ceramic

被引：22

作者：

Wang, Shengjin ^{[1
]}

Yang, Zhihua ^{[1
]}

Duan, Xiaoming ^{[1
]}

Jia, Dechang ^{[1
]}

Ma, Feixiang ^{[1
]}

Sun, Boqian ^{[1
]}

Zhou, Yu ^{[1
]}

机构：

[1] Harbin Inst Technol, Inst Adv Ceram, Harbin 150001, Peoples R China

来源：

INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY | 2014年 / 11卷 / 05期

基金：

中国国家自然科学基金;

关键词：

SILICON-NITRIDE; MECHANICAL-PROPERTIES; DIELECTRIC-PROPERTIES; COMPRESSIVE STRENGTH; MICROSTRUCTURE; BEHAVIOR; SIZE;

D O I：

10.1111/ijac.12134

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Porous Si3N4-Si2N2O-BN ceramic was fabricated at 1750 degrees C using Si3N4, BN, and (NH4)(2)HPO4 as starting materials. During the sintering process, oxygen from the decomposed products of (NH4)(2)HPO4 would bond Si and N in the liquid phase to form Si2N2O. The microstructure and properties of the porous ceramics were investigated. With the (NH4)(2)HPO4 content varied from 10 to 50 vol.%, porosity of the porous Si3N4-Si2N2O-BN ceramic increased from 43.5% to 51%. The microstructure, mechanical, and dielectric properties was well controlled by adjusting (NH4)(2)HPO4 contents. The present technique offers a more simple way of synthesizing porous Si3N4-Si2N2O-BN ceramics.

引用

页码：832 / 838

页数：7

共 35 条

[1] Pressureless sintering of α-Si3N4 porous ceramics using a H3PO4 pore-forming agent [J].

Chen, Fei ;

Shen, Qiang ;

Yan, Faqiang ;

Zhang, Lianmeng .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2007, 90 (08) :2379-2383

[2] Characterisation of porous silicon nitride materials produced with starch [J].

Díaz, A ;

Hampshire, S .

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2004, 24 (02) :413-419

[3] Fabrication of silicon nitride silicon oxynitride in-situ composites [J].

Emoto, H ;

Mitomo, M ;

Wang, CM ;

Hirosturu, H ;

Inaba, T .

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1998, 18 (05) :527-533

[4] High performance porous silicon nitrides [J].

Inagaki, Y ;

Kondo, N ;

Ohji, T .

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2002, 22 (14-15) :2489-2494

[5] Characterization of porous silicon nitride/silicon oxynitride composite ceramics produced by sol infiltration [J].

Jia, Dechang ;

Shao, Yingfeng ;

Liu, Boyang ;

Zhou, Yu .

MATERIALS CHEMISTRY AND PHYSICS, 2010, 124 (01) :97-101

[6] CALCULATION OF QUASIBINARY AND QUASITERNARY OXYNITRIDE SYSTEMS .3. [J].

KAUFMAN, L .

CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 1979, 3 (04) :275-291

[7] Mechanical and dielectric properties of porous Si2N2O-Si3N4 in situ composites [J].

Li ShuQin ;

Pei YuChen ;

Yu ChangQing ;

Li JiaLu .

CERAMICS INTERNATIONAL, 2009, 35 (05) :1851-1854

[8] Microstructure and Properties of Porous Si3N4 Ceramics with a Dense Surface [J].

Li, Xiangming ;

Yin, Xiaowei ;

Zhang, Litong ;

Pan, Tianhao .

INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY, 2011, 8 (03) :627-636

[9] Mechanical and dielectric properties of porous Si3N4-SiC(BN) ceramic [J].

Li, Xiangming ;

Zhang, Litong ;

Yin, Xiaowei ;

Yu, Zhaoju .

JOURNAL OF ALLOYS AND COMPOUNDS, 2010, 490 (1-2) :L40-L43

[10]

Lin FH, 2000, J BIOMED MATER RES, V51, P157, DOI 10.1002/(SICI)1097-4636(200008)51:2<157::AID-JBM3>3.0.CO

← 1 2 3 4 →