catena-poly[[[μ-sulfato-dicopper(I)]-di-μ-4,4′-bipyridine-1:1′κ2N,N′;2:2′κ2N,N′]tetrahydrate]

被引：5

作者：

Zhang, XM

Fang, RQ

Wu, HS

Ng, SW ^{[1
]}

机构：

[1] Shanxi Normal Univ, Sch Chem & Mat Sci, Linfen 041004, Peoples R China

[2] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2004年 / 60卷

关键词：

D O I：

10.1107/S1600536804014801

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the crystal structure of the yellow copper( I) compound, {[Cu-2(SO4)(C10H8N2)(2)] . 4H(2)O}(n), one [(C10H8N2)(2)Cu](n) chain is stacked over another [Cu ... Cu = 3.180 (1) Angstrom]; the two chains are bridged by SO4 groups through two Cu - O bonds into a double-chain motif. The SO4 groups are located alternately on opposite sides of the double chain and lie on twofold rotation axes. The disordered solvent water molecules occupy the space between the double chains. The Cu-I atom exists in a T-shaped environment.

引用

页码：M990 / M992

页数：3

共 15 条

[11] Anionic and neutral metal-4,4′- bipyridine networks. Synthesis, structures and thermal properties of one- and three-dimensional coordination polymers constructed by metal salts and 4,4′-bipyridine [J].