NMR investigations of phase transition in aqueous polymer solutions and gels

被引：108
作者：
Spevacek, Jiri [1 ]
机构：
[1] Acad Sci Czech Republic, Inst Macromol Chem, CR-16206 Prague 6, Czech Republic
来源：
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE | 2009年 / 14卷 / 03期
关键词：
Phase transition; Aqueous polymer solution; Hydrogel; NMR; POLY(N-ISOPROPYLACRYLAMIDE) COLLOIDAL MICROGELS; CROSS-LINKED POLY(N-ISOPROPYLACRYLAMIDE); METHYL ETHER)/D2O SOLUTIONS; N-ISOPROPYLACRYLAMIDE; SOLVENT INTERACTIONS; H-1-NMR RELAXATION; GRAFT-COPOLYMERS; D2O SOLUTIONS; THERMOREVERSIBLE POLYMERS; SIDE-CHAINS;
D O I：
10.1016/j.cocis.2008.10.003
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The use of NMR spectroscopy in investigations of phase transitions in aqueous polymer solutions and gels is reviewed. Results on this subject as obtained mostly for thermoresponsive polymers (e.g., poly(N-isopropylacrylamide) and its copolymers, poly(N-isopropylmethacrylamide) and its copolymers, poly(vinyl methyl ether)) from temperature dependences of (1)H and (13)C NMR spectra, spin-lattice and spin-spin relaxation times, diffusion coefficients and NMR images are discussed. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码：184 / 191
页数：8
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