NMR investigations of phase transition in aqueous polymer solutions and gels

被引：110

作者：

Spevacek, Jiri ^{[1
]}

机构：

[1] Acad Sci Czech Republic, Inst Macromol Chem, CR-16206 Prague 6, Czech Republic

来源：

CURRENT OPINION IN COLLOID & INTERFACE SCIENCE | 2009年 / 14卷 / 03期

关键词：

Phase transition; Aqueous polymer solution; Hydrogel; NMR; POLY(N-ISOPROPYLACRYLAMIDE) COLLOIDAL MICROGELS; CROSS-LINKED POLY(N-ISOPROPYLACRYLAMIDE); METHYL ETHER)/D2O SOLUTIONS; N-ISOPROPYLACRYLAMIDE; SOLVENT INTERACTIONS; H-1-NMR RELAXATION; GRAFT-COPOLYMERS; D2O SOLUTIONS; THERMOREVERSIBLE POLYMERS; SIDE-CHAINS;

D O I：

10.1016/j.cocis.2008.10.003

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The use of NMR spectroscopy in investigations of phase transitions in aqueous polymer solutions and gels is reviewed. Results on this subject as obtained mostly for thermoresponsive polymers (e.g., poly(N-isopropylacrylamide) and its copolymers, poly(N-isopropylmethacrylamide) and its copolymers, poly(vinyl methyl ether)) from temperature dependences of (1)H and (13)C NMR spectra, spin-lattice and spin-spin relaxation times, diffusion coefficients and NMR images are discussed. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：184 / 191

页数：8

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