Characterization of O-trimethylsilyl oximes of trisaccharides by gas chromatography-mass spectrometry

被引：22

作者：

Brokl, Michal ^{[1
]}

Cristina Soria, Ana ^{[2
]}

Martinez-Castro, Isabel ^{[1
]}

Luz Sanz, Maria ^{[1
]}

Isabel Ruiz-Matute, Ana ^{[1
]}

机构：

[1] CSIC, Inst Quim Organ Gen, E-28006 Madrid, Spain

[2] CSIC, Inst Fermentac Ind, E-28006 Madrid, Spain

来源：

JOURNAL OF CHROMATOGRAPHY A | 2009年 / 1216卷 / 22期

关键词：

Gas chromatography-mass spectrometry; Trimethylsilyl oximes; Trisaccharides; DISACCHARIDES; DERIVATIVES; OLIGOSACCHARIDES; IDENTIFICATION; LACTULOSE; ETHERS; HONEY;

D O I：

10.1016/j.chroma.2009.03.069

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Gas chromatography (CC) data (linear retention indices and relative areas) and mass spectra (most representative m/z fragments) of 12 reducing trisaccharides as trimethylsilyl oximes (TMSO) and four non-reducing as trimethylsilyl (TMS) ethers have been described for the first time and related to their structural features. Some trends have been observed: earlier elution of non-reducing compounds and fructotrioses; aldotrioses hearing the reducing end with link in position 6 showing the highest retention. Abundance of several fragment tons and their ratios were useful for trisaccharide characterization; some of these features seem to be useful for the characterization of new trisaccharides. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：4689 / 4692

页数：4

共 21 条

[1] Synthesis of oligosacccharides derived from lactulose and Pectinex Ultra SP-L
Cardelle-Cobas, Alejandra
Martinez-Villaluenga, Cristina
Villamiel, Mar
Olano, Agustin
Corzo, Nieves
[J]. JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2008, 56 (09) : 3328 - 3333
[2] COTE GL, 2003, P AM CHEM SOC S OL F, P75
[3] ANALYSIS OF TRIMETHYLSILYL DERIVATIVES OF CARBOHYDRATES BY GAS CHROMATOGRAPHY AND MASS SPECTROMETRY
DEJONGH, DC
RADFORD, T
HRIBAR, JD
HANESSIA.S
BIEBER, M
DAWSON, G
SWEELEY, CC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (07) : 1728 - &
[4] SYN AND ANTI FORMS OF SOME MONOSACCHARIDE O-METHYL OXIMES - C-13-NMR AND GLC STUDY
FUNCKE, W
VONSONNTAG, C
[J]. CARBOHYDRATE RESEARCH, 1979, 69 (MAR) : 247 - 251
[5] Characteristic fragmentation patterns of the trimethylsilyl and trimethylsilyl-oxime derivatives of various saccharides as obtained by gas chromatography coupled to ion-trap mass spectrometry
Fuzfai, Zs.
Boldizsar, I.
Molnar-Perl, I.
[J]. JOURNAL OF CHROMATOGRAPHY A, 2008, 1177 (01) : 183 - 189
[6] GAS-CHROMATOGRAPHIC RETENTION OF CARBOHYDRATE TRIMETHYLSILYL ETHERS .4. DISACCHARIDES
GARCIARASO, A
PAEZ, MI
MARTINEZCASTRO, I
SANZ, J
CALVO, MM
[J]. JOURNAL OF CHROMATOGRAPHY, 1992, 607 (02): : 221 - 225
[7] GAS-LIQUID CHROMATOGRAPHY OF TRIMETHYLSILYL DISACCHARIDES
HAVERKAMP, J
VLIEGENT.JF
KAMERLIN.JP
[J]. JOURNAL OF CHROMATOGRAPHY, 1971, 59 (02): : 281 - +
[8] Simultaneous quantitation of mono-, di- and trisaccharides by GC-MS of their TMS ether oxime derivatives .2. In honey
Horvath, K
MolnarPerl, I
[J]. CHROMATOGRAPHIA, 1997, 45 (1) : 328 - 335
[9] MASS SPECTROMETRY OF PERTRIMETHYLSILYL ALDOSYL OLIGOSACCHARIDES
KAMERLIN.JP
VLIEGENT.JF
VINK, J
RIDDER, JJD
[J]. TETRAHEDRON, 1971, 27 (18) : 4275 - +
[10] MASS-SPECTROMETRY OF PERTRIMETHYLSILYL OLIGOSACCHARIDES CONTAINING FRUCTOSE UNITS
KAMERLING, JP
VINK, J
VLIEGENTHART, JF
DERIDDER, JJ
[J]. TETRAHEDRON, 1972, 28 (16) : 4375 - +

← 1 2 3 →