Proof of the formation of hydroperoxymethyl formate in the ozonolysis of ethene: Synthesis and FT-IR spectra of the authentic compound

被引:38
作者
Thamm, J [1 ]
Wolff, S [1 ]
Turner, WV [1 ]
Gab, S [1 ]
Thomas, W [1 ]
Zabel, F [1 ]
Fink, EH [1 ]
Becker, KH [1 ]
机构
[1] BERG UNIV GESAMTHSCH WUPPERTAL,DEPT CHEM PHYS,D-42119 WUPPERTAL,GERMANY
关键词
D O I
10.1016/0009-2614(96)00625-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Hydroperoxymethyl formate is synthesized by the ozonolysis of ethyl vinyl ether in solution and characterized by NMR and MS. The FT-IR spectra of the compound in the gas phase are in accord with those of an intermediate in the gas-phase ozonolysis of ethene.
引用
收藏
页码:155 / 158
页数:4
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