Silver and gold-catalyzed multicomponent reactions

被引:110
作者
Abbiati, Giorgio [1 ]
Rossi, Elisabetta [1 ]
机构
[1] Univ Milan, Dipartimento Sci Farmaceut, Sez Chim Gen & Organ A Marchesini, I-20133 Milan, Italy
来源
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 10卷
关键词
A(3)-coupling; gold; multicomponent reactions; silver; 3-COMPONENT COUPLING REACTION; ALDEHYDE-ALKYNE-AMINE; PERIODIC MESOPOROUS ORGANOSILICA; ONE-POT SYNTHESIS; HIGHLY EFFICIENT; TERMINAL ALKYNES; VINYLOGOUS MANNICH; FACILE SYNTHESIS; GREEN SYNTHESIS; PROPARGYLAMINES;
D O I
10.3762/bjoc.10.46
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Silver and gold salts and complexes mainly act as soft and carbophilic Lewis acids even if their use as s-activators has been rarely reported. Recently, transformations involving Au(I)/Au(III)-redox catalytic systems have been reported in the literature. In this review we highlight all these aspects of silver and gold-mediated processes and their application in multicomponent reactions.
引用
收藏
页码:481 / 513
页数:33
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