Preparation of acrylated and urethanated triacylglycerols

被引：51

作者：

Pelletier, H ^{[1
]}

Gandini, A ^{[1
]}

机构：

[1] Domaine Univ, EFPG, INGP, UMR 5518,Lab Genie Proc Papetiers, F-38402 St Martin Dheres, France

来源：

EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY | 2006年 / 108卷 / 05期

关键词：

acrylated castor oil; epoxidized acrylated soybean oil; functionalization; styrenic-urethane castor oil; vegetable oils;

D O I：

10.1002/ejlt.200501168

中图分类号：

TS2 [食品工业];

学科分类号：

0832 ;

摘要：

Since a preliminary study had shown that the internal double bonds present on the unsaturated aliphatic chains were too unreactive for any viable polymerization process, chemical modifications were investigated involving the grafting of polymerizable oil. Acrylate and styrenic urethane moieties were successfully appended on these triacylglycerol molecules. The grafting processes are described and the modified oils characterized, leading to the discussion of some structure-property relationships.

引用

页码：411 / 420

页数：10

共 22 条

[1]

BIERMANN H, 1988, ANGEW CHEM INT EDIT, V27, P41

[2]

Biermann U, 2000, ANGEW CHEM INT EDIT, V39, P2206, DOI 10.1002/1521-3773(20000703)39:13<2206::AID-ANIE2206>3.0.CO

[3]

2-P

[4] Castor-acrylated monomer 1H- and 13C-nuclear magnetic resonance spectral assignments [J].

Brister, EH ;

Jarrett, W ;

Thames, SF .

JOURNAL OF APPLIED POLYMER SCIENCE, 2001, 82 (08) :1850-1854

[5] Synthesis and characterization of monomers and polymers for adhesives from methyl oleate [J].

Bunker, SP ;

Wool, RP .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2002, 40 (04) :451-458

[6] EPOXIDIZED TRIGLYCERIDES AS RENEWABLE MONOMERS IN PHOTOINITIATED CATIONIC POLYMERIZATION [J].

CRIVELLO, JV ;

NARAYAN, R .

CHEMISTRY OF MATERIALS, 1992, 4 (03) :692-699

[7]

Decker C, 1996, EUR POLYM J, V32, P549, DOI 10.1016/0014-3057(95)00192-1

[8] Synthesis and polymerization of the bromoacrylated plant oil triglycerides to rigid, flame-retardant polymers [J].

Eren, T ;

Küsefoglu, SH .

JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 91 (04) :2700-2710

[9] Hydroxymethylation and polymerization of plant oil triglycerides [J].

Eren, T ;

Küsefoglu, SH .

JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 91 (06) :4037-4046

[10]

Guo A, 2000, J POLYM SCI POL CHEM, V38, P3900, DOI 10.1002/1099-0518(20001101)38:21<3900::AID-POLA70>3.0.CO

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