High-spin Schiff-base dinuclear iron(III) complexes bridged by N-oxide ligands

被引：18

作者：

Nemec, Ivan ^{[1
]}

Boca, Roman ^{[1
]}

Gembicky, Milan ^{[2
]}

Dlhan, Lubor ^{[1
]}

Herchel, Radovan ^{[3
]}

Renz, Franz ^{[4
]}

机构：

[1] Slovak Tech Univ, Inst Inorgan Chem FCHPT, SK-81237 Bratislava, Slovakia

[2] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA

[3] Palacky Univ, Dept Inorgan Chem, CZ-77147 Olomouc, Czech Republic

[4] Leibniz Univ Hannover, Inst Inorgan Chem, D-30167 Hannover, Germany

来源：

INORGANICA CHIMICA ACTA | 2009年 / 362卷 / 13期

关键词：

Schiff-base ligands; N-oxide ligands; Iron(III) complex; Structure; Magnetism; Mossbauer spectroscopy; CROSSOVER; CHLORIDE;

D O I：

10.1016/j.ica.2009.06.057

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Synthesis and structure of dinuclear complexes [{Fe-III(L-5)}b{Fe-III(L-5)}](BPh4)(2), where L-5 is a pentadentate Schiff-base ligand, b is a bidentate N-oxide bridging ligand based on bipyridine, is reported. Magnetic behavior is investigated in terms of the magnetic susceptibility, magnetization, and Mossbauer spectroscopy revealing that the complexes are high-spin over the whole temperature region. (C) 2009 Elsevier B. V. All rights reserved.

引用

页码：4754 / 4759

页数：6

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