A Rubber Elastic Low-molecular-weight Organogel

被引：2
|
作者：
Shirakawa, Michihiro [1 ]
Fujita, Norifumi [2 ]
Takada, Akihiko [3 ]
Shinkai, Seiji [4 ]
机构：
[1] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Nishi Ku, Fukuoka 8128581, Japan
[2] Meijo Univ, Fac Sci & Technol, Dept Appl Chem, Tempaku Ku, Nagoya, Aichi 4688502, Japan
[3] Kyushu Univ, Dept Adv Device Mat, Inst Mat Chem & Engn, Kasuga, Fukuoka 8168581, Japan
[4] Sojo Univ, Fac Engn, Dept Nanosci, Kumamoto 8600082, Japan
来源：
CHEMISTRY LETTERS | 2014年 / 43卷 / 08期
关键词：
PERYLENE BISIMIDE DYES; PI-CONJUGATED SYSTEMS; AGGREGATION MODE; ORGANIC MEDIA; GEL; PORPHYRIN; GELATORS; CREATION; ORGANIZATION; ASSEMBLIES;
D O I：
10.1246/cl.140278
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A low-molecular-weight gel prepared from a Cu complex of a protoporphyrin a derivative exhibits an unusual elastic behavior as revealed by rheological studies. It possesses rubber elasticity despite the formation of LMOG by noncovalent molecular stacking. This is due to the feature of the present system that the gel fibers behave similarly to covalent polymers without bundling.
引用
收藏
页码：1330 / 1332
页数：3
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