On the importance of the free energy for elasticity under pressure

被引:41
作者
Marcus, PM [1 ]
Ma, H
Qiu, SL
机构
[1] IBM Corp, Thomas J Watson Res Ctr, Yorktown Hts, NY 10598 USA
[2] Florida Atlantic Univ, Dept Phys, Alloy Res Ctr, Boca Raton, FL 33431 USA
关键词
D O I
10.1088/0953-8984/14/28/101
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
It is shown that the theory of elasticity under hydrostatic pressure p at zero temperature is unified and simplified by the use of the Gibbs free energy G, rather than the energy E. The minima of G, but not of E, give the equilibrium structure; the second derivatives of G, but not of E, with respect to strains at the equilibrium structure give the zero-temperature elastic constants; the stability of a phase at p is then determined by the same Born stability conditions used at p = 0 when applied to the elastic constants from G. Examples are noted of mistakes due to use of E rather than G.
引用
收藏
页码:L525 / L528
页数:4
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