Photoluminescence properties of Eu3+:MgAl2O4 powder phosphor

被引：99

作者：

Omkaram, I. ^{[1
]}

Rao, B. Vengala ^{[1
]}

Buddhudu, S. ^{[1
]}

机构：

[1] Sri Venkateswara Univ, Dept Phys, Tirupati 517502, Andhra Pradesh, India

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2009年 / 474卷 / 1-2期

关键词：

Phosphors; Solid-state reaction; X-ray diffraction; Luminescence; MGAL2O4; SPINEL; LUMINESCENT PROPERTIES; ALUMINATE PHOSPHOR; OPTICAL-PROPERTIES; GREEN PHOSPHOR; GEL SYNTHESIS; IONS; EU2+; DY3+; INTENSITIES;

D O I：

10.1016/j.jallcom.2008.06.140

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This paper reports the results of MgAl2O4:Eu3+ red emitting phosphor which has been characterized by X-ray diffraction, FESEM, FT-IR and photoluminescence spectra. The ultraviolet excitation at 393 nm has been chosen because it has got maximum excitation intensity. These phosphors show different emissions of Eu3+ corresponding to D-5(0) -> F-7(J=0,1,2,3,4) transitions which lie in the wavelength range from 550 to 700 nm. One particular transition D-5(0) -> F-7(2) which is centered at 615 nm has been known as a hypersensitive emission which obeys the selection rule of (Delta J = 2) resulting in a strong and intense red emission. The lifetime, luminescence quenching has been discussed and the mechanism involved in the generation of red emission has also been explained. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：565 / 568

页数：4

共 42 条

[31] OPTICAL SPECTRUM OF CR3+ IONS IN SPINELS [J].

WOOD, DL ;

IMBUSCH, GF ;

MACFARLA.RM ;

KISLIUK, P ;

LARKIN, DM .

JOURNAL OF CHEMICAL PHYSICS, 1968, 48 (11) :5255-&

[32] ZEEMAN EFFECT OF CR3+ IN ZNAL2O4 [J].

WOOD, DL ;

BURKE, WE ;

VANUITER.LG .

JOURNAL OF CHEMICAL PHYSICS, 1969, 51 (05) :1966-&

[33] Influence of microwave process on photoluminescence of europium-doped strontium aluminate phosphor prepared by a novel sol-gel-microwave process [J].

Wu, Suli ;

Zhang, Shufen ;

Yang, Jinzong .

MATERIALS CHEMISTRY AND PHYSICS, 2007, 102 (01) :80-85

[34] A bluish green barium aluminate phosphor for PDP application [J].

Xing, De-Song ;

Gong, Meng-Lian ;

Qiu, Xue-Qing ;

Yang, Dong-Jie ;

Cheah, Kok-Wai .

MATERIALS LETTERS, 2006, 60 (27) :3217-3220

[35]

YAMAMOTO H, 1997, J LUMIN, V287, P72

[36] A new luminescent material, Sr2SnO4:Eu3+ [J].

Yang, H. M. ;

Shi, J. X. ;

Gong, M. L. .

JOURNAL OF ALLOYS AND COMPOUNDS, 2006, 415 (1-2) :213-215

[37] Optical properties and valence change of europium ions in a sol-gel Al2O3-B2O3-SiO2 glass by femtosecond laser pulses [J].

You, H ;

Nogami, M .

JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (29) :13980-13984

[38] Citrate-gel synthesis and luminescent properties of ZnGa2O4 doped with Mn2+ and EU3+ [J].

Yu, M ;

Lin, J ;

Zhou, YH ;

Wang, SB .

MATERIALS LETTERS, 2002, 56 (06) :1007-1013

[39] Synthesis and characterization of nano MgAl2O4 spinel by the co-precipitated method [J].

Zawrah, M. F. ;

Hamad, H. ;

Meky, S. .

CERAMICS INTERNATIONAL, 2007, 33 (06) :969-978

[40] Synthesis and VUV photoluminescence of green-emitting X2-Y2SiO5:Tb3+ phosphor for PDP application [J].

Zhang, Zhan Hui ;

Wang, Yu Hua ;

Hao, Yan ;

Liu, Wen Jing .

JOURNAL OF ALLOYS AND COMPOUNDS, 2007, 433 (1-2) :L12-L14

← 1 2 3 4 5 →