Efficient Pd(0)-catalyzed hydrosilylation of alkynes with triorganosilanes

被引：0

作者：

Motoda, D ^{[1
]}

Shinokubo, H ^{[1
]}

Oshima, K ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Sakyo Ku, Kyoto 6068501, Japan

来源：

SYNLETT | 2002年 / 09期

关键词：

hydrosilylation; palladium; phosphine; alkyne; alkene;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An electron-rich Pd(0) complex, a Pd-2(dba)(3).CHCl3-tricyclohexylphosphine combination catalyzes highly efficient hydrosilylation of alkynes at room temperature with Ph3SiH or Ph2MeSiH without solvents. The regioselectivity of this process is higher than that with the conventional Pt(0)-catalyzed hydrosilylation.

引用

页码：1529 / 1531

页数：3

共 33 条

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