A new acylamide MOF showing uncommon ten-fold interpenetration

被引:14
作者
Dang, Li-long [1 ]
Li, Jian-qiang [1 ]
Liu, Shu-juan [1 ]
Luo, Ming-biao [1 ]
Luo, Feng [1 ]
机构
[1] E China Inst Technol, Coll Biol Chem & Mat Sci, Fuzhou 344000, Jiangxi, Peoples R China
基金
中国国家自然科学基金;
关键词
MOFs; Solvo(hydro)thermal method; Dia net; 10-fold interpenetration; NETWORKS; COPPER(I);
D O I
10.1016/j.inoche.2014.03.030
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In this work, we obtained a novel three-dimensional acylamide MOF, namely Zn(L) (BPDC)center dot H2O(1, BPDC2- = biphenyl-4,4'-dicarboxylate, L = N,N'-diphenyl-terephthalamide) by solvo(hydro)thermal method. This polymer was characterized by single-crystal X-ray diffraction, thermogravimetry and solid-state luminescence analysis. The outstanding structural feature of compound I is 4-connected dia net with uncommon 10-fold interpenetration in the [5 + 51 manner. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:30 / 32
页数:3
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