A two-dimensional copper polymer constructed from rod-shaped ferromagnetic secondary building units

被引：10
作者：
Wang, Zhao-Xi [1 ]
Li, Ming-Xing [1 ]
Shao, Min [2 ]
Xiao, Hong-Ping [3 ]
机构：
[1] Shanghai Univ, Coll Sci, Dept Chem, Shanghai 200444, Peoples R China
[2] Shanghai Univ, Instrumental Anal & Res Ctr, Shanghai 200444, Peoples R China
[3] Wenzhou Univ, Sch Chem & Mat Engn, Wenzhou 325027, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2009年 / 12卷 / 03期
关键词：
Azide-copper; Crystal structure; Magnetic properties; SBUs; END-TO-END; METAL-ORGANIC FRAMEWORKS; ON AZIDE BRIDGES; MAGNETIC-PROPERTIES; COORDINATION POLYMERS; CRYSTAL-STRUCTURE; BLOCKS SBBS; DESIGN; COMPLEXES; LIGANDS;
D O I：
10.1016/j.inoche.2008.12.014
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
On the basis of rod-shaped secondary building units (SBUs), a novel two-dimensional (2D) azide-copper polymer, [Cu-3(N-3)(4)(anol)(2)](infinity) (1: anol = aminoethanol), was synthesized and structurally characterized. Complex 1 is a neutral 2D coordination network consisting of trinuclear coppe (II) clusters [Cu-3(N-3)(4)(anol)(2)] connected with the bridge of end-end (EE) azide group. Magnetic data analysis shows that a metamagnetic behavior is observed for 1 which is associated with significant ferromagnetic coupling intracluster over 4 K. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：201 / 203
页数：3
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