Crystallization and dissolution Behavior of L(+) calcium and zinc lactate in ethanol-water solvent

被引:9
作者
Cao, XJ [1 ]
Lee, HJ [1 ]
Yun, HS [1 ]
Koo, YM [1 ]
机构
[1] E China Univ Sci & Technol, Dept Biochem Engn, State Key Lab Bioreactor Engn, Shanghai 200237, Peoples R China
关键词
L(+) calcium lactate; L(+) zinc lactate; crystallization; dissolution;
D O I
10.1007/BF02698418
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Crystallization and dissolution behavior of L(+) calcium and zinc lactate in 50% ethanol-water solution was studied. The effects of stirring, standing, ultrasonic wave, and temperature on the crystallization of L(+) calcium and zinc lactate were evaluated. It was found that standing had a positive effect on crystallization of L(+) calcium and zinc lactate, while stirring promoted dissolution of crystallized particles and resulted in high residual concentration in mother liquor. The application of ultrasonic wave did not influence much or. crystallization process. L(+) calcium and zinc lactate crystallized easily at 5degreesC; however, complete crystallization tool: more than 72 hours. These two salts dissolved rapidly and reached equilibrium within 1 hour.
引用
收藏
页码:301 / 304
页数:4
相关论文
共 15 条
[1]   Solubilities of calcium and zinc lactate in water and water-ethanol mixture [J].
Cao, X ;
Lee, HJ ;
Yun, HS ;
Koo, YM .
KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2001, 18 (01) :133-135
[2]  
CHEN B, 1995, J HUAQIAO U NATURAL, V16, P318
[3]  
JIN QR, 1994, FERMENTATION TECHNOL
[4]  
KEOOY PD, 1997, Patent No. 5599551
[5]  
Kricheldorf HR, 1998, MACROMOL CHEM PHYS, V199, P1089, DOI 10.1002/(SICI)1521-3935(19980601)199:6<1089::AID-MACP1089>3.0.CO
[6]  
2-S
[7]   Polylactones .37. Polymerizations of L-lactide initiated with Zn(II) L-lactate and other resorbable Zn salts [J].
Kricheldorf, HR ;
Damrau, DO .
MACROMOLECULAR CHEMISTRY AND PHYSICS, 1997, 198 (06) :1753-1766
[8]  
Mullin JW., 1993, CRYSTALLIZATION
[9]  
Schwach G, 1998, POLYM INT, V46, P177, DOI 10.1002/(SICI)1097-0126(199807)46:3<177::AID-PI937>3.0.CO
[10]  
2-S