Crosslinking free-radical polymerization of dimethacrylates in the presence of branched poly(methyl methacrylate)

被引：8

作者：

Kurmaz, S. V. ^{[1
]}

Ozhiganov, V. V. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Oblast, Russia

来源：

POLYMER SCIENCE SERIES B | 2009年 / 51卷 / 5-6期

基金：

俄罗斯基础研究基金会;

关键词：

POLYMERS;

D O I：

10.1134/S1560090409050029

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The kinetics of polymerization of ethylene glycol and 1,6-hexanediol dimethacrylates in the presence of branched and linear PMMAs, 1-decanethiol, and methylphenyl sulfide has been studied by isothermal calorimetry. The sol-gel analysis of 1,6-hexanediol polydimethacrylates prepared in the absence and presence of the branched PMMA is performed. The effect of the branched PMMA on the diffusion-sorption, mechanical, thermomechanical, and optical properties of polydimethacrylates is investigated. It has been established that, in the crosslinking free-radical polymerization of dimethacrylates, the branched PMMA serves both as a reactive macromonomer and a chemically inert additive-polymer filler.

引用

页码：157 / 165

页数：9

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