Thermodynamic properties of liquid Al-Sn-Zn alloys: A possible new lead-free solder material

被引:24
作者
Knott, S [1 ]
Mikula, A [1 ]
机构
[1] Univ Vienna, Inst Anorgan Chem, A-1090 Vienna, Austria
关键词
aluminum-tin-zinc ternary system; thermodynamic properties; lead-free solder materials; electromotive force measurements;
D O I
10.2320/matertrans.43.1868
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Because of its potential to be used as a lead free solder material the thermodynamic properties of the liquid Al-Sn-Zn system were investigated. Using an appropriate galvanic cell, the partial free energies of Al were determined as a function of concentration and temperature. Thermodynamic properties were obtained for 30 alloys. Their composition was situated on three cross-sections with constant ratios of Sn:Zn 2: 1, 1:1 and 1:2. The integral Gibbs energy and the integral enthalpy for the ternary system at 973 K were calculated by Gibbs-Duhem integration.
引用
收藏
页码:1868 / 1872
页数:5
相关论文
共 48 条
[1]  
ALABYSHEV AF, 1954, ZH PRIKL KHIM, V27, P851
[2]  
ANSARA I, 1998, THERMOCHEMICAL DATAB, P347
[3]   Al-Zn-Sn phase diagram - Calorimetric study of the isobaric invariants [J].
Aragon, E ;
Vincent, D ;
Zahra, AM ;
Sebaoun, A .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 1999, 55 (01) :271-282
[4]  
ARAGON E, 1998, J THERM ANAL, V51, P1
[5]   THERMODYNAMIC ACTIVITY OF ZINC IN DILUTE ZINC-TIN ALLOYS BY TORSION-EFFUSION METHOD [J].
CHANG, YA ;
WILHELM, GC ;
LATHROP, M ;
GYUK, I .
ACTA METALLURGICA, 1971, 19 (08) :795-&
[6]   A THERMODYNAMIC ANALYSIS OF THE AL-ZN SYSTEM AND PHASE-DIAGRAM CALCULATION [J].
CHEN, SL ;
CHANG, YA .
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 1993, 17 (02) :113-124
[7]   THE THERMODYNAMIC PROPERTIES OF LIQUID TERNARY CADMIUM SOLUTIONS [J].
ELLIOTT, JF ;
CHIPMAN, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (06) :2682-2693
[8]  
Fiorani M., 1955, GAZZ CHIM ITAL, V85, P607
[9]  
Fries S. G., 1991, USERS ASPECTS PHASE, P280
[10]  
GEFFKEN R, 1967, T METALL SOC AIME, V239, P1151