Ion-molecular reactions of free phenylium ions, generated by tritium β-decay with bidentate arenes

被引：6
|
作者：
Shchepina, NE [1 ]
Nefedov, VD
Toropova, MA
Avrorin, VV
Lewis, SB
Mattson, B
机构：
[1] Perm Univ, Inst Nat Sci, Lab Radiochem, Perm, Russia
[2] St Petersburg State Univ, Dept Radiochem, St Petersburg, Russia
[3] Creighton Univ, Dept Chem, Omaha, NE 68178 USA
来源：
TETRAHEDRON LETTERS | 2000年 / 41卷 / 01期
关键词：
radiation chemistry; labeling; halogens; halogen compounds;
D O I：
10.1016/S0040-4039(99)02019-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Generation of free phenylium ions, obtained by tritium beta-decay and their ion-molecular reactions with bidentate arenes are described. The elaborated nuclear-chemical method has been used for the synthesis of tritium labeled organic derivatives using halobenzenes. Two alternative pathways for interaction of the phenylium ion with the bidentate arene, addition to the lone pair of the halogen or substitution on the aromatic ring, were revealed. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：25 / 27
页数：3
相关论文
共 50 条
  • [21] KINETICS OF GAS-PHASE EXCHANGED ION-MOLECULAR REACTIONS
    KARACHEVTSEV, GV
    MARUTKIN, AZ
    SAVKIN, VV
    USPEKHI KHIMII, 1982, 51 (11) : 1849 - 1874
  • [22] ION-MOLECULAR REACTIONS OF ETHANE AT LOW ELECTRON-ENERGY
    DUNBAR, RC
    SHEN, J
    OLAH, GA
    JOURNAL OF CHEMICAL PHYSICS, 1972, 56 (08): : 3794 - &
  • [23] Gas phase derivations of endohedral metallofullerenes by ion-molecular reactions
    Chinese Acad of Sciences, Changchun, China
    Fullerene Sci Technol, 7 (1461-1477):
  • [24] EFFECT OF ION-MOLECULAR REACTIONS ON THE OPTICAL-BREAKDOWN IN GASES
    NASTOYASHCHII, AF
    KVANTOVAYA ELEKTRONIKA, 1980, 7 (01): : 170 - 178
  • [25] Gas phase derivations of endohedral metallofullerenes by ion-molecular reactions
    Sun, DY
    Liu, ZY
    Liu, ZQ
    Guo, XH
    Hao, CY
    Xu, WG
    Liu, SY
    FULLERENE SCIENCE AND TECHNOLOGY, 1997, 5 (07): : 1461 - 1477
  • [26] Ion-molecular reactions in gaseous phase studied in the groups of periodical system
    Zahradnik, R
    CHEMICKE LISTY, 1997, 91 (07): : 461 - 465
  • [27] ION-CYCLOTRON RESONANCE STUDY OF ION-MOLECULAR REACTIONS OF VOLATILE ORGANOMETALLIC COMPOUNDS
    DUNBAR, RC
    ENNEVER, JF
    FACKLER, JP
    INORGANIC CHEMISTRY, 1973, 12 (11) : 2734 - 2736
  • [28] DETERMINATION OF THE FORMATION OF BIO-IONS AND BIO2-IONS BY THE ION-MOLECULAR EQUILIBRIA TECHNIQUE
    KUZNETSOVA, OV
    SEMENIKHIN, VI
    RUDNYI, EB
    SIDOROV, LN
    ZHURNAL FIZICHESKOI KHIMII, 1992, 66 (12): : 3160 - 3165
  • [29] RADIOCHEMISTRY OF ION-MOLECULAR REACTIONS OF FREE METHYL-CATIONS WITH BENZENE AND ALKYL-BENZENES IN GAS-PHASE
    NEFEDOV, VD
    SINOTOVA, EN
    SHISHKUNOV, VA
    ZHURNAL ORGANICHESKOI KHIMII, 1976, 12 (07): : 1491 - 1495
  • [30] COMBINED OSCILLATING-RECTILINEAR ENERGY EXCHANGE DURING ION-MOLECULAR REACTIONS
    KARACHEVTSEV, GV
    KHIMICHESKAYA FIZIKA, 1986, 5 (07): : 875 - 877
12345