Fe3O4/C composites synthesized from Fe-based xerogels for anode materials of Li-ion batteries

被引：16
作者：
Chen, Xiao Yan [1 ]
Liu, Bin Hong [1 ]
Li, Zhou Peng [2 ]
机构：
[1] Zhejiang Univ, Dept Mat Sci & Eng, Hangzhou 310027, Zhejiang, Peoples R China
[2] Zhejiang Univ, Dept Chem & Biol Eng, Hangzhou 310027, Zhejiang, Peoples R China
来源：
SOLID STATE IONICS | 2014年 / 261卷
基金：
中国国家自然科学基金;
关键词：
Fe-based xerogel; Nanocomposite; Cyclic stability; Anode; Li-ion batteries; HIGH-PERFORMANCE ANODE; ELECTRODE MATERIALS; ELECTROCHEMICAL PERFORMANCE; LITHIUM STORAGE; HIGH-CAPACITY; CARBON; ALPHA-FE2O3; CHALLENGES; OXIDE; NANOCRYSTALS;
D O I：
10.1016/j.ssi.2014.04.004
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In this study, Fe3O4/carbon nanocomposites as anode materials of Li-ion batteries were synthesized through heating hierarchically porous Fe-based xerogels under N-2 atmosphere. The pyrolysis of amorphous Fe-xerogel base materials resulted in the simultaneous formation of Fe3O4/C composites, in which Fe3O4 particles of less than 50 nm were uniformly dispersed and embedded in a porous carbon matrix. Due to the favorable nanostructure, the synthesized Fe3O4/C composites with a proper carbon content of 18.8 wt.% exhibited good electrochemical performance including high capacity and rate capability as well as much enhanced cyclic stability. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：45 / 52
页数：8
相关论文
共 37 条
[11]   LiFePO4/CA cathode nanocomposite with 3D conductive network structure for Li-ion battery [J].
Jiang, Qiong ;
Xu, Yunlong ;
Zhao, Chongjun ;
Qian, Xiuzhen ;
Zheng, Shaowei .
JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2012, 16 (04) :1503-1508
[12]   Synthesis of Monolithic Hierarchically Porous Iron-Based Xerogels from Iron(III) Salts via an Epoxide-Mediated Sol-Gel Process [J].
Kido, Yasuki ;
Nakanishi, Kazuki ;
Miyasaka, Akira ;
Kanamori, Kazuyoshi .
CHEMISTRY OF MATERIALS, 2012, 24 (11) :2071-2077
[13]   Superparamagnetic Fe3O4 nanocrystals@graphene composites for energy storage devices [J].
Li, Baojun ;
Cao, Huaqiang ;
Shao, Jin ;
Qu, Meizhen ;
Warner, Jamie H. .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (13) :5069-5075
[14]   Hybrids of iron oxide/ordered mesoporous carbon as anode materials for high-capacity and high-rate capability lithium-ion batteries [J].
Li, Zhaoqiang ;
Wang, Xuekun ;
Wang, Changbin ;
Yin, Longwei .
RSC ADVANCES, 2013, 3 (38) :17097-17104
[15]   Manganese Oxide/Carbon Aerogel Composite: an Outstanding Supercapacitor Electrode Material [J].
Lin, Yu-Hsun ;
Wei, Te-Yu ;
Chien, Hsing-Chi ;
Lu, Shih-Yuan .
ADVANCED ENERGY MATERIALS, 2011, 1 (05) :901-907
[16]   Magnetite/carbon core-shell nanorods as anode materials for lithium-ion batteries [J].
Liu, Hao ;
Wang, Guoxiu ;
Wang, Jiazhao ;
Wexler, David .
ELECTROCHEMISTRY COMMUNICATIONS, 2008, 10 (12) :1879-1882
[17]   Nitrogen-doped carbon-encapsulation of Fe3O4 for increased reversibility in Li+ storage by the conversion reaction [J].
Ma, Yue ;
Zhang, Chao ;
Ji, Ge ;
Lee, Jim Yang .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (16) :7845-7850
[18]   Li-alloy based anode materials for Li secondary batteries [J].
Park, Cheol-Min ;
Kim, Jae-Hun ;
Kim, Hansu ;
Sohn, Hun-Joon .
CHEMICAL SOCIETY REVIEWS, 2010, 39 (08) :3115-3141
[19]   Nano-sized transition-metaloxides as negative-electrode materials for lithium-ion batteries [J].
Poizot, P ;
Laruelle, S ;
Grugeon, S ;
Dupont, L ;
Tarascon, JM .
NATURE, 2000, 407 (6803) :496-499
[20]   Layer Structured α-Fe2O3 Nanodisk/Reduced Graphene Oxide Composites as High-Performance Anode Materials for Lithium-Ion Batteries [J].
Qu, Jin ;
Yin, Ya-Xia ;
Wang, Yong-Qing ;
Yan, Yang ;
Guo, Yu-Guo ;
Song, Wei-Guo .
ACS APPLIED MATERIALS & INTERFACES, 2013, 5 (09) :3932-3936
1234