Emissive pattern formation by the photoreaction of poly(p-phenylene vinylene)

被引:3
作者
Kim, Yuna [1 ]
Yun, Chijung [1 ]
Jadhav, Parashuram [1 ]
You, Jungmok [1 ]
Kim, Eunkyoung [1 ]
机构
[1] Yonsei Univ, Dept Chem & Biomol Engn, Seoul 120749, South Korea
关键词
MDMO-PPV; Photocyclization; Micropatterning; Photoreaction; Light emitting; LIGHT-EMITTING DEVICES; ELECTROLUMINESCENT POLYMER; PPV; ENHANCEMENT; SYSTEMS;
D O I
10.1016/j.cap.2008.12.007
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The vinylene unit of a p-phenylene polymer was photo-oxidized under atmospheric oxygen to provide emittive patterns. Thin films of poly[2-methoxy-5-(3,7-dimethyloctyloxy)-p-phenylene vinylene] (MDMO-PPV) were directly photo-patterned by UV light through a photo-mask having I pm-wide lines. The absorption and fluorescence studies on the MDMO-PPV film by UV irradiation indicated that the photo-patterning was mainly originated from the oxidation of the vinylic bonds to give carbonyl (C=O) containing polymers. The patterned MDMO-PPV film was applied to an electroluminescent cell, which showed 20 mu m-wide luminescent line patterns at applied potential of 5 V. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:1088 / 1092
页数:5
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