The exclusivity of multivalency in dynamic covalent processes

被引：64
作者：
Badjic, JD
Cantrill, SJ
Grubbs, RH [1 ]
Guidry, EN
Orenes, R
Stoddart, JF
机构：
[1] CALTECH, Arnold & Mabel Beckman Lab Chem Synth, Div Chem & Chem Engn, Pasadena, CA 91125 USA
[2] Univ Calif Los Angeles, Calif Nanosyst Inst, Los Angeles, CA 90095 USA
[3] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 25期
关键词：
metathesis; molecular recognition; NMR spectroscopy; supramolecular chemistry;
D O I：
10.1002/anie.200453963
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Less is more: It is much less efficient to synthesize both components of a multivalent recognition site separately than it is to use one multivalent component to act as a template for the catalytically orchestrated construction of the other component, as demonstrated by the formation of the mechanically interlocked, triply threaded molecular bundle shown. The situation is reiniscent of nature.
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收藏
页码：3273 / 3278
页数：6
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