Allylation of carbonyl compounds mediated by nanometer-sized bismuth in water

被引：18

作者：

Xu, XL

Zha, ZG

Miao, Q

Wang, ZY ^{[1
]}

机构：

[1] Columbia Univ, Dept Chem, New York, NY 10027 USA

[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China

来源：

SYNLETT | 2004年 / 07期

关键词：

allylation; carbonyl compounds; water; aromatic; stereoselectivity;

D O I：

10.1055/s-2004-822924

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

It is found that nanometer-sized bismuth mediates the allylation of carbonyl compounds in water to afford the corresponding homoallylic alcohol in high yields. Nanometer-sized bismuth is much more effective than regular bismuth powder in this reaction.

引用

页码：1171 / 1174

页数：4

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