A molybdenum based metallomicellar catalyst for controlled and selective sulfoxidation reactions in aqueous medium

被引：67

作者：

Chakravarthy, Rajan Deepan ^{[1
]}

Ramkumar, Venkatachalam ^{[1
]}

Chand, Dillip Kumar ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Madras 600036, Tamil Nadu, India

来源：

GREEN CHEMISTRY | 2014年 / 16卷 / 04期

关键词：

30-PERCENT HYDROGEN-PEROXIDE; S BOND-CLEAVAGE; ORGANIC-SYNTHESIS; ROOM-TEMPERATURE; RADICAL CATIONS; SOLVENT-FREE; PART; OXIDATION; SULFIDES; SULFONES;

D O I：

10.1039/c3gc42245c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A surfactant based molybdenum system that exhibits catalytic activity for sulfoxidation reactions of various organic sulfides in aqueous medium has been developed and comprehensively characterized using IR, XRD, NMR, ESI-MS, DLS and TEM. The catalyst showcases remarkable selectivity for the preparation of both sulfoxides and sulfones in the range of good to excellent yields. Furthermore, the catalyst showed a high degree of tolerance towards various sensitive functional groups such as hydroxyl, acetal, aldehyde, amine, imine, oxime, cyano and alkene.

引用

页码：2190 / 2196

页数：7

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