A novel method for preparing high surface area copper zirconia catalysts Influence of the preparation variables

被引：33

作者：

Aguila, Gonzalo ^{[1
]}

Jimenez, Javier ^{[1
]}

Guerrero, Sichem ^{[1
]}

Gracia, Francisco ^{[1
]}

Chornik, Boris ^{[2
]}

Quinteros, Sergio ^{[1
]}

Araya, Paulo ^{[1
]}

机构：

[1] Univ Chile, Dept Ingn Quim & Biotecnol, Ctr Invest Interdisciplinaria Avanzada Ciencia Ma, Santiago, Chile

[2] Univ Chile, Dept Fis, Fac Ciencias Fis & Matemat, Santiago 8370415, Chile

来源：

APPLIED CATALYSIS A-GENERAL | 2009年 / 360卷 / 01期

关键词：

Reflux treatment; Copper; Zirconia; CO oxidation; Methanol reforming; OXYGEN VACANCY; CUO/ZRO2; CATALYSTS; METHANOL SYNTHESIS; SULFATED ZIRCONIA; CARBON-MONOXIDE; OXIDATION; SUPPORT; CO; DIGESTION; ZRO2;

D O I：

10.1016/j.apcata.2009.03.014

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new and straightforward method to prepare high surface area Cu-ZrO2 catalysts is presented. This method considers a reflux treatment of commercial hydrous zirconia in the presence of a copper-containing NH4OH solution. The method allows the stabilization of high surface area ZrO2 supports with highly dispersed CuO throughout the support surface. It was observed that the addition of copper by this reflux treatment decreases the crystalline character of the ZrO2 support and increases the surface area. The potential catalytic application of these materials is exemplified with the CO oxidation and methanol reforming reactions. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：98 / 105

页数：8

共 27 条

[21] The effects of zirconia morphology on methanol synthesis from CO and H2 over Cu/ZrO2 catalysts Part II.: Transient-response infrared studies [J].