Paper: An Effective Substrate for the Enhancement of Thermoelectric Properties in PEDOT: PSS

被引:53
作者
Jiang, Qinglin [1 ]
Liu, Congcong [1 ]
Xu, Jingkun [1 ]
Lu, Baoyang [1 ]
Song, Haijun [1 ]
Shi, Hui [1 ]
Yao, Yuanyuan [1 ]
Zhang, Long [1 ]
机构
[1] Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Organ Chem, Nanchang 330013, Peoples R China
基金
中国国家自然科学基金;
关键词
composites; conducting polymers; paper; PEDOT:PSS; thermoelectric; thin films; ELECTRICAL-CONDUCTIVITY; POLY(3,4-ETHYLENEDIOXYTHIOPHENE); FILMS; PERFORMANCE; BEHAVIOR;
D O I
10.1002/polb.23482
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A novel strategy via paper as an effective substrate has been introduced as a thermoelectric material in this work. Free-standing poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS)/paper composite films are conveniently prepared by a one-step method of directly writing PEDOT:PSS solution on paper, making the process simple, rapid, and facile. The free-standing composite films display excellent flexibility, light weight, soaking stability in water, and great potential in large-scale production. Improved thermoelectric properties are obtained in PEDOT:PSS/paper composite films, owing to the simultaneously enhanced Seebeck coefficient (30.6 V K-1) and electrical conductivity, and a low thermal conductivity (0.16 W m(-1) K-1) compared with pristine PEDOT:PSS films. The results indicate that paper as an effective substrate is suitable for the preparation of high-performance and flexible thermoelectric materials. (c) 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2014, 52, 737-742
引用
收藏
页码:737 / 742
页数:6
相关论文
共 35 条
[1]  
Andersson P, 2002, ADV MATER, V14, P1460, DOI 10.1002/1521-4095(20021016)14:20<1460::AID-ADMA1460>3.0.CO
[2]  
2-S
[3]  
Bejan A., 2003, HEAT TRANSFER HDB, P1338
[4]   RETRACTED: Towards polymer-based organic thermoelectric generators (Retracted Article) [J].
Bubnova, Olga ;
Crispin, Xavier .
ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (11) :9345-9362
[5]  
Cotterill P., 1976, Recrystallization and grain growth in metals
[6]   Inkjet printing of polymers: State of the art and future developments [J].
de Gans, BJ ;
Duineveld, PC ;
Schubert, US .
ADVANCED MATERIALS, 2004, 16 (03) :203-213
[7]   New directions for low-dimensional thermoelectric materials [J].
Dresselhaus, Mildred S. ;
Chen, Gang ;
Tang, Ming Y. ;
Yang, Ronggui ;
Lee, Hohyun ;
Wang, Dezhi ;
Ren, Zhifeng ;
Fleurial, Jean-Pierre ;
Gogna, Pawan .
ADVANCED MATERIALS, 2007, 19 (08) :1043-1053
[8]   Research progress on polymer-inorganic thermoelectric nanocomposite materials [J].
Du, Yong ;
Shen, Shirley Z. ;
Cai, Kefeng ;
Casey, Philip S. .
PROGRESS IN POLYMER SCIENCE, 2012, 37 (06) :820-841
[9]   Conducting Polymers: Efficient Thermoelectric Materials [J].
Dubey, Nidhi ;
Leclerc, Mario .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2011, 49 (07) :467-475
[10]  
Goldsmid H. J., 1964, Thermoelectric Refrigeration