Hydrated HCl Clusters, HCl(H2O)1-3, in Helium Nanodroplets: Studies of Free OH Vibrational Stretching Modes

被引：47

作者：

Skvortsov, Dmitry ^{[2
]}

Lee, Seung Jun ^{[1
]}

Choi, Myong Yong ^{[1
]}

Vilesov, Andrey F. ^{[2
]}

机构：

[1] Gyeongsang Natl Univ, Res Inst Nat Sci, Jinju 660701, South Korea

[2] Univ So Calif, Dept Chem, Los Angeles, CA 90089 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 2009年 / 113卷 / 26期

基金：

新加坡国家研究基金会;

关键词：

WATER CLUSTERS; LIQUID-HELIUM; INFRARED-SPECTRUM; HYDROGEN-CHLORIDE; H3N-HCL COMPLEX; ICE SURFACES; GAS-PHASE; SPECTROSCOPY; IONIZATION; DYNAMICS;

D O I：

10.1021/jp811497c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this work, infrared laser spectroscopy in helium droplets is used to study the solvation of HCl with small water clusters. Clusters of HCl(H2O)(n) With n = 1-3 and (HCl)(2)H2O have been identified in the free OH. stretching spectral range of 3680-3820 cm(-1). The assignment of the infrared vibrational bands of the clusters is aided by ab initio calculations.

引用

页码：7360 / 7365

页数：6

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