Platinum corroles

被引：66

作者：

Alemayehu, Abraham B. ^{[1
,2
]}

Vazquez-Lima, Hugo ^{[1
,2
]}

Beavers, Christine M. ^{[3
]}

Gagnon, Kevin J. ^{[3
]}

Bendix, Jesper ^{[4
]}

Ghosh, Abhik ^{[1
,2
]}

机构：

[1] Arctic Univ Norway, Dept Chem, N-9037 Tromso, Norway

[2] Arctic Univ Norway, UiT, Ctr Theoret & Computat Chem, N-9037 Tromso, Norway

[3] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Adv Light Source, Berkeley, CA 94720 USA

[4] Univ Copenhagen, Dept Chem, DK-2100 Copenhagen, Denmark

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 76期

关键词：

TRANSITION-METAL CENTERS; PARAMAGNETIC-RESONANCE; NONINNOCENT; METALLOCORROLES; REACTIVITY; CHEMISTRY; INSIGHTS; SPECTRA; COPPER;

D O I：

10.1039/c4cc02548b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Platinum has been inserted into corroles for the first time and three oxidized Pt-IV(corrole(center dot 2-))ArAr' complexes have been structurally characterized. The Soret maxima of these complexes exhibit an unusually strong dependence on the meso-aryl substituents on the corrole, indicating aryl -> corrole(center dot 2-) charge transfer character in these transitions.

引用

页码：11093 / 11096

页数：4

共 26 条

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