A simple high-yielding synthesis of ferrocene-1',-diylbis-(methyltrimethylammonium iodide)

被引：21

作者：

Glidewell, C

Royles, BJL

Smith, DM

机构：

[1] School of Chemistry, University of St. Andrews, St. Andrews

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 527卷 / 1-2期

基金：

英国工程与自然科学研究理事会;

关键词：

ferrocene; sodium phenoxide; iodomethane;

D O I：

10.1016/S0022-328X(96)06644-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new simple, high-yielding procedure has been developed for the synthesis of ferrocene-1, 1'-diylbis(methyltrimethylammonium iodide) 2. Ferrocene is dilithiated using n-butyllithium/TMEDA and then reacted with Eschenmoser's salt to form the bis(dimethylaminomethyl) derivative 6 in good yield. Treatment with iodomethane gives rise to the corresponding ammonium salt 2 in excellent yield. Reaction of this bis-ammonium salt with sodium phenoxide affords the 1, 1'-bis(phenoxymethyl) compound 10.

引用

收藏

页码：259 / 261

页数：3

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