Neutral coordination polymers of Cobalt(II), Copper(II), Zinc(II) and Manganese(II) β-diketonate complexes with fluorescent anthracene dipyridine: Synthesis, structure and luminescence properties

被引：11

作者：

Jia, Li-Mei ^{[1
]}

Tong, Jin ^{[1
]}

Yu, Shu-Yan ^{[1
]}

机构：

[1] Beijing Univ Technol, Coll Environm & Energy Engn, Beijing Key Lab Green Catalysis & Separat, Lab Self Assembly Chem,Dept Chem & Chem Ind, Beijing 100124, Peoples R China

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2018年 / 355卷

关键词：

Coordination polymer; Fluorescent linker; Crystal structure; Luminescence property; METAL-ORGANIC FRAMEWORK; CRYSTAL-STRUCTURE; SUPRAMOLECULAR ISOMERISM; CU(II) COMPLEXES; SCHIFF-BASES; CONSTRUCTION; PYRAZINE; CO(II); CADMIUM(II); NICKEL(II);

D O I：

10.1016/j.jphotochem.2017.10.041

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A series of polynuclear complexes (2-5, 7) and dinuclear complex (6) of first row transition metals have been synthesized by the reaction of beta-diketonate metal complexes including Mn(II), Zn(II), Co(II) and Cu(II) with the fluorescent anthracene ligand 9,10-Bis(4-pyridyl)anthracene (bpanth). All complexes were characterized by single-crystal X-ray structure analysis, FT-IR, UV-vis and fluorescence spectroscopy. Distrinct and interesting luminescent properties of 2-7 were investigated in the solution state. (C) 2017 Elsevier B.V. All rights reserved.

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页码：84 / 93

页数：10

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