Study of dielectric relaxation and hydrogen bonding interaction in binary mixtures of methoxy polyethylene glycol and water

被引:0
|
作者
Mathpati, R. N. [1 ]
Shinde, S. B. [1 ]
Rathod, D. G. [1 ]
Kanse, K. S. [1 ]
Joshi, Y. S. [1 ]
机构
[1] Lal Bahadur Shastri Mahavidyalaya, Dept Phys & Elect, Dharmabad 431809, India
关键词
Complex permittivity; Dielectric relaxation; TDR; Thermodynamic properties; TIME-DOMAIN REFLECTOMETRY; HETEROGENEOUS INTERACTION; MOLECULAR INTERACTION; PERMITTIVITY; SPECTROSCOPY; TEMPERATURE; ALCOHOL; AMIDES;
D O I
暂无
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The complex permittivity spectra of binary mixtures of methoxy polyethylene glycol (Polyethylene glycol monomethylether 350) and water over entire concentrations and at different temperatures have been measured using time domain technique in the frequency range of 10 MHz to 30 GHz. The spectra have been fitted to Cole-Davidson model using non linear least square fit method to obtain the dielectric parameters. The non linear behaviour of dielectric parameters suggest intermolecular interaction among the unlike molecules. Excess properties and Bruggeman factor confirm the contribution of hydrogen bonding interactions among the solute-solvent mixtures. Thermodynamic properties of these binary mixtures are also discussed.
引用
收藏
页码:282 / 287
页数:6
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